1467099-22-4Relevant articles and documents
Dimers with thermally activated delayed fluorescence (TADF) emission in non-doped device
Chen, Xing,Khan, Aziz,Zou, Sheng-Nan,Li, Yun,Tian, Qi-Sheng,Zhong, Cheng,Fung, Man-Keung,Jiang, Zuo-Quan,Liao, Liang-Sheng
, p. 4792 - 4798 (2021)
Two novel TADF molecules, with donor#1-σ-donor#2-π-acceptor (D1-σ-D2-π-A) conformation, were designed and synthesized through-bond charge transfer (TBCT) and through-space charge transfer (TSCT). These two materials differ only in the D1 groups with triphenylamine forSFCCNand 10-phenyl-10H-phenoxazine forSFCCNO. Due to the unconjugated linkage, both materials showed very similar emission to that from D2-π-A TBCT effect in dilute solution.SFCCNOcan form dimers at the aggregation state and exhibit intermolecular D1/A TSCT emission because of the planar D1 conformation. Therefore, a non-doped device based onSFCCNOexhibited efficiencies of 12.9% at 100 cd m?2and 10.4% at 1000 cd m?2, which are much higher than theSFCCNbased device.
Control of conjugation degree via position engineering to highly efficient phosphorescent host materials
Zhang, Ye-Xin,Zhang, Lei,Cui, Lin-Song,Gao, Chun-Hong,Chen, Hua,Li, Qian,Jiang, Zuo-Quan,Liao, Liang-Sheng
, p. 3748 - 3751 (2014)
The C3 meta-position of fluorene is utilized to construct high-triplet energy compounds. Incorporating a spiroacridine structure, two new host materials SAFDPA and SAFCz were facilely obtained. Their thermal and photophysical properties are fully investigated. The best efficiencies of 19.4%/21.5% of blue/white devices are achieved by SAFCz.
Compound for organic electroluminescent device, and application thereof
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Paragraph 0024-0025, (2021/07/24)
The invention relates to a compound for an organic electroluminescent device. The structure of the compound is shown as a formula (I), in the formula, R1-R6 are respectively and independently selected from a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group and a substituted or unsubstituted heteroaryl group. The compound disclosed by the invention is of a boron main body structure, and the boron element is easier to form a structure with an electronic defect characteristic than the carbon element, so that the derivative of the compound has relatively good electron withdrawing capability. In addition, a spirofluorene unit with the characteristic of good thermal stability is introduced into a boron structural unit, so that the bipolar boron compound with high triplet energy can be obtained; besides, the compound contains a stable multi-element ring structure, so that the stability of the material is greatly improved, the molecular weight is relatively large, and the glass-transition temperature of the material is increased, thereby ensuring that the material is not decomposed after being evaporated for a long time.