1467101-59-2

Basic information

• Product Name: C₇H₄N₂O₆*C₁₀H₉N₃
• Synonyms: C₇H₄N₂O₆*C₁₀H₉N₃
• CAS NO: 1467101-59-2
• Molecular Weight: 383.32
• Mol File: 1467101-59-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₇H₄N₂O₆*C₁₀H₉N₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₇H₄N₂O₆*C₁₀H₉N₃(1467101-59-2)
• EPA Substance Registry System: C₇H₄N₂O₆*C₁₀H₉N₃(1467101-59-2)

Safety Data

• Hazardous Substances Data: 1467101-59-2(Hazardous Substances Data)

Upstream product

• 1202-34-2 di(pyridin-2-yl)amine 
• 610-30-0 2,4-dinitrobenzoic acid 

Relevant articles and documents

Proton-transfer supramolecular salts based on proton sponge 2,2′-dipyridylamine

Reactions between proton sponge 2,2′-dipyridylamine and acidic synthons (2,4-dinitrobenzoic acid, 3,4-dinitrobenzoic acid and picronitric acid) afford three proton-transfer supramolecular ammonium salts, (2,4-dinitrobenzoate)?(2,2′-dipyridylammonium) (1), (3,4-dinitrobenzoate)?(2,2′-dipyridylammonium)?(H 2O) (2) and (picrate)?(2,2′-dipyridylammonium) (3), respectively. During solution crystallization, the proton transfers from the organic acid to the nitrogen atom in the pyridyl ring. It is found that monoprotonated dpaH+ has an asymmetrical intramolecular hydrogen bond (IHB) N-H+?N, which results in the intramolecular S(6) ring. All supramolecular architectures of 1-3 involve extensive classical hydrogen bonds and display a three-dimensional (3D) framework structure. Robust hydrogen bonding interactions generate various intermolecular ring motifs.