146862-76-2

Basic information

• Product Name: (E)-methyl trans-4,5-(isopropylidenedioxy)-6-(benzyloxy)-2-hexenoate
• Synonyms: (E)-methyl trans-4,5-(isopropylidenedioxy)-6-(benzyloxy)-2-hexenoate
• CAS NO: 146862-76-2
• Molecular Weight: 306.359
• Mol File: 146862-76-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-methyl trans-4,5-(isopropylidenedioxy)-6-(benzyloxy)-2-hexenoate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-methyl trans-4,5-(isopropylidenedioxy)-6-(benzyloxy)-2-hexenoate(146862-76-2)
• EPA Substance Registry System: (E)-methyl trans-4,5-(isopropylidenedioxy)-6-(benzyloxy)-2-hexenoate(146862-76-2)

Safety Data

• Hazardous Substances Data: 146862-76-2(Hazardous Substances Data)

Upstream product

• 5927-18-4 trimethyl phosphonoacetate 
• 163058-80-8 (4S,5S)-5-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde 
• 78469-77-9 (4S,5S)-4-benzyloxymethyl-5-hydroxymethyl-2,2-dimethyl-1,3-dioxolane 
• 81028-12-8 (4S,5R)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-5-carboxaldehyde 
• 88738-78-7 bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 80697-33-2 (R)-6-Benzyloxy-5-hydroxy-hexanoic acid methyl ester 
• 146862-82-0 (E)-(R)-6-Benzyloxy-5-hydroxy-hex-3-enoic acid methyl ester 
• 608-66-2 D-galactitol 
• 81028-17-3 (2R,3R)-3-((4R,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,3-dihydroxy-propionic acid methyl ester 

Relevant articles and documents

Stereoselective synthesis of 5-O-carbamoylpolyoxamic acid by [2,3]- Wittig-Still rearrangement

Stereoselective [2,3]-Wittig rearrangement of E- and Z-allylic stannyl ethers derived from an isopropylidene L-threitol derivative has been investigated. The E-isomer exhibited best diastereoselectivity and the resulting rearrangement product has been converted to protected polyoxamic acid, an amino acid component of many bioactive polyoxins.

Synthesis of Saccharides and Related Polyhydroxylated Natural Products. 1. Simple Alditols

A new approach to sugar synthesis is demonstrated through syntheses of tetritols, pentitols, and hexitols; titanium-catalyzed asymmetric epoxidation and a new selective opening reaction of 2,3-epoxy alcohols play essential roles.