146962-10-9

Basic information

• Product Name: (E)-(2S,5S,6R)-Methyl 2-acetoxy-6,7-bis(benzyloxy)-5-methylhept-3-enoate
• Synonyms: (E)-(2S,5S,6R)-Methyl 2-acetoxy-6,7-bis(benzyloxy)-5-methylhept-3-enoate
• CAS NO: 146962-10-9
• Molecular Weight: 426.51
• Mol File: 146962-10-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-(2S,5S,6R)-Methyl 2-acetoxy-6,7-bis(benzyloxy)-5-methylhept-3-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(2S,5S,6R)-Methyl 2-acetoxy-6,7-bis(benzyloxy)-5-methylhept-3-enoate(146962-10-9)
• EPA Substance Registry System: (E)-(2S,5S,6R)-Methyl 2-acetoxy-6,7-bis(benzyloxy)-5-methylhept-3-enoate(146962-10-9)

Safety Data

• Hazardous Substances Data: 146962-10-9(Hazardous Substances Data)

Upstream product

• 146962-06-3 (2R,3R)-(E)-Methyl 3-(dimethylphenylsilyl)-2-hydroxyhex-4-enoate 
• 133323-23-6 (2R,3R)-(E)-3-(Dimethylphenylsilyl)-2-hydroxyhex-4-enoic acid 
• 14642-79-6 benzyloxy-trimethylsilane 
• 60656-87-3 benzyloxyacetoaldehyde 
• 143446-41-7 (2R,3R)-(E)-Methyl 2-acetoxy-3-(dimethylphenylsilyl)-hex-4-enoate 

Relevant articles and documents

Sequential Diastereoselective Addition and Palladium(II)-Catalyzed Allylic Acetate Transposition of syn- and anti-α-Acetoxy-β-silyl-(E)-hex-4-enoates with Achiral Acetals. Asymmetric Synthesis of Differentiated Syn and Anti 1,3-Diol Synthons

syn- and anti-Methyl α-acetoxy-β-(dimethylphenylsilyl)-(E)-hex-4-enoates, (2R,3R)-8a and (2S,3R)-8b, undergo highly diastereo- and enantioselective addition reactions with aldehydes and acetals 11 catalyzed by the action of trimethylsilyl trifluoromethane