1469880-15-6Relevant articles and documents
Blue LED Irradiation of Iodonium Ylides Gives Diradical Intermediates for Efficient Metal-free Cyclopropanation with Alkenes
Chidley, Tristan,Jameel, Islam,Rizwan, Shafa,Peixoto, Philippe A.,Pouységu, Laurent,Quideau, Stéphane,Hopkins, W. Scott,Murphy, Graham K.
, p. 16959 - 16965 (2019/11/11)
A facile and highly chemoselective synthesis of doubly activated cyclopropanes is reported where mixtures of alkenes and β-dicarbonyl-derived iodonium ylides are irradiated with light from blue LEDs. This metal-free synthesis gives cyclopropanes in yields
N-Iodosuccinimide-Initiated Spirocyclopropanation of Styrenes with 1,3-Dicarbonyl Compound for the Synthesis of Spirocyclopropanes
Qian, Ping,Du, Bingnan,Song, Ruichun,Wu, Xiaodong,Mei, Haibo,Han, Jianlin,Pan, Yi
, p. 6546 - 6553 (2016/08/16)
Herein is reported an N-iodosuccinimide-initiated spirocyclopropanation reaction of styrenes with 1,3-dicarbonyl compounds in the presence of white LED light. The reaction proceeds via two C-H and two C-I bond cleavage event, along with two C-C bond forma