147217-94-5

Basic information

• Product Name: Benzaldehyde, 4-[(2,5-dimethoxyphenyl)hydroxymethyl]-2,5-dimethoxy-
• CAS NO: 147217-94-5
• Molecular Formula: C18H20O6
• Molecular Weight: 332.353
• Mol File: 147217-94-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 4-[(2,5-dimethoxyphenyl)hydroxymethyl]-2,5-dimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 4-[(2,5-dimethoxyphenyl)hydroxymethyl]-2,5-dimethoxy-(147217-94-5)
• EPA Substance Registry System: Benzaldehyde, 4-[(2,5-dimethoxyphenyl)hydroxymethyl]-2,5-dimethoxy-(147217-94-5)

Safety Data

• Hazardous Substances Data: 147217-94-5(Hazardous Substances Data)

Upstream product

• 60732-17-4 2,5-dimethoxybenzyl bromide 
• 93-02-7 2,5-dimethoxybenzaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 

Relevant articles and documents

Phenyl-Carbonyl Coupling Reactions Promoted by Samarium Diiodide and Hexamethylphosphoramide

By mediation of samarium diiodide and hexamethylphosphoramide, benzaldehydes and acetophenones underwent self- and cross-couplings to give the products having linkages at the para-carbons of phenyl rings and the carbonyl groups. The phenyl-carbonyl coupling of 2,5-dimethoxybenzaldehyde generated a Sm(III)-enolate intermediate, which was trapped by alkyl halides in a stereospecific manner to give uncommon 1,4-dialkyl-2,5-cyclohexadiene-1-carboxaldehydes. The benzaldehydes bearing tethered carbonyl chains proceeded with intramolecular phenyl-carbonyl couplings to afford fused benzocycles.