147356-80-7

Basic information

• Product Name: Benzene, (4-cyclopropylidenecyclohexyl)-
• CAS NO: 147356-80-7
• Molecular Formula: C15H18
• Molecular Weight: 198.308
• Mol File: 147356-80-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, (4-cyclopropylidenecyclohexyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (4-cyclopropylidenecyclohexyl)-(147356-80-7)
• EPA Substance Registry System: Benzene, (4-cyclopropylidenecyclohexyl)-(147356-80-7)

Safety Data

• Hazardous Substances Data: 147356-80-7(Hazardous Substances Data)

Upstream product

• 4894-75-1 1-phenyl-4-cyclohexanone 
• 3607-17-8 3-bromopropyltriphenylphosphonium bromide 
• 14633-95-5 triphenylphosphonium cyclopropylide 

Downstream Products

• 1198091-60-9 C₃₀H₃₂O₂ 
• 10289-45-9 4-propyl-1,1'-biphenyl 
• 1416331-78-6 3-(4-phenylcyclohexylidene)-1,2-dithiolane 
• 1416332-07-4 3-(4-phenylcyclohexylidene)-1,2-diselenolane 
• 1361201-38-8 C₁₆H₁₈O₂ 
• 1361201-37-7 C₁₆H₁₈O₂ 
• 1334325-34-6 C₂₅H₂₇N₃O 
• 1228299-33-9 C₂₄H₂₈O₂ 
• 1192024-30-8 1-(1-iodocyclopropyl)-4-phenylcyclohexanol 
• 1160784-70-2 C₂₇H₂₈Se₂ 
• 1160784-76-8 C₂₉H₃₂S₂ 
• 1160784-75-7 C₂₈H₃₀SSe 
• 1000680-15-8 C₃₆H₃₄O 
• 835903-40-7 C₂₇H₂₈Se₂ 

Relevant articles and documents

Biscyclopropyl titanocene: A novel reagent for the synthesis of alkylidene and vinyl cyclopropanes

Alkylidene cyclopropane derivatives are obtained by reaction of biscyclopropyl titanocene with several types of carbonyl compounds, including aldehydes, ketones and esters. In some cases the isomeric vinyl cyclopropane products are also obtained. Biscyclopropyl titanocene also reacts with alkynes forming, after acidification, the corresponding vinyl cyclopropanes.

Synthesis of Fluorinated Homoallylic Compounds by Fluoroalkyl Radical Mediated Ring Opening of Methylenecyclopropanes

The fluoroalkyl (Rf) radical mediated ring opening of methylenecyclopropanes (MCPs) 1 and subsequent atom transfer were investigated. In the first part, a copper-initiated radical reaction of Rf-X (X = I, Br) with MCP 1 gave homoallylic halides 2 in excellent yields. Similarly, radical reaction of the RfTMS/CsF/PhI(OCOR)2 system with MCP 1 led to homoallylic alcohol esters 3 in moderate to good yields. An efficient synthesis of fluoroalkyl (Rf)-substituted homoallylic halides 2 and homoallylic alcohol esters 3 by fluoroalkyl radical mediated ring opening of methylenecyclopropanes (MCPs) 1 followed by an atom-transfer process is developed.