14753-39-0

Basic information

• Product Name: cis-1,2-Epoxy-4-tert-Butylcyclohexane
• Synonyms: cis-1,2-Epoxy-4-tert-Butylcyclohexane
• CAS NO: 14753-39-0
• Molecular Weight: 154.252
• Mol File: 14753-39-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-1,2-Epoxy-4-tert-Butylcyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1,2-Epoxy-4-tert-Butylcyclohexane(14753-39-0)
• EPA Substance Registry System: cis-1,2-Epoxy-4-tert-Butylcyclohexane(14753-39-0)

Safety Data

• Hazardous Substances Data: 14753-39-0(Hazardous Substances Data)

Upstream product

• 2228-98-0 4-tert-butylcylohexene 

Downstream Products

• 120447-54-3 (+/-)-cis-4-tert-butyl-trans-2-(4-phenylpiperidino)cyclohexanol hydrochloride 
• 3178-22-1 tert-butylcyclohexane 
• 937-05-3 cis-4-tert-butyl-1-cyclohexanol 
• 10488-10-5 cis-3-tert-butylcyclohexanone 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 86476-17-7 trans-2-iodo-cis-5-tBu-cyclohexanol 
• 23058-03-9 trans-2-bromo-cis-5-tBu-cyclohexanol 
• 17002-13-0 trans-2-chloro-cis-5-tBu-cyclohexanol 
• 2228-98-0 4-tert-butylcylohexene 
• 71962-03-3 (1R,2R,4S)-(-)-tert-Butylcyclohexane-1,2-diol 
• 71962-02-2 (1S,2S,4R)-(+)-tert-Butylcyclohexane-1,2-diol 

Relevant articles and documents

Convenient synthesis of 1,3-dithiolane-2-thiones: Cyclic trithiocarbonates as conformational locks

A series of novel 1,3-dithiolane-2-thiones, or cyclic trithiocarbonates, has been prepared by a new simple procedure: a treatment of the corresponding epoxides with the commercially available potassium ethyl xanthogenate, KSC(S)OEt. The stereochemistry of the products was determined by 1H NMR and in some cases by single-crystal X-ray data. Cyclohexane-based 1,3- dithiolane-2-thiones revealed a trans-fusion of the carbo- and hetero-cycles. The products obtained from the mono-substituted cyclohexene oxides demonstrated an axial position of the substituents. Thus the epoxide transformation into trithiocarbonate can be used as a method for locking cyclic compounds in unstable conformations.ARKAT-USA, Inc.