14753-97-0Relevant articles and documents
Nickel, manganese, cobalt, and iron-catalyzed deprotonative arene dimerization
Truong, Thanh,Alvarado, Joseph,Tran, Ly Dieu,Daugulis, Olafs
, p. 1200 - 1203 (2010)
"Chemical Equation Presented" A number of first-row transition metal salts catalyze deprotonative dimerization of acidic arenes. Under the atmosphere of oxygen, nickel, manganese, cobalt, and iron chlorides have been shown to dimerize five- and six-membered ring heterocycles as well as electron-poor arenes. Both tetramethylpiperidide and dicyclohexylamide bases can be employed; however, the former afford slightly higher yields.
Room-temperature copper-catalyzed oxidation of electron-deficient arenes and heteroarenes using air
Liu, Qiang,Wu, Pan,Yang, Yuhong,Zeng, Ziqi,Liu, Jie,Yi, Hong,Lei, Aiwen
supporting information; experimental part, p. 4666 - 4670 (2012/06/30)
No pressure: The oxidation of aromatic C-H bonds at room temperature was realized through a copper-catalyzed "oxygenase-type" oxidation of arenes and heteroarenes in the presence of air (see scheme). The reaction involves an oxygen-atom transfer from O2 in the air onto the substrates. Copyright
