14758-37-3 Usage
Molecular structure
2-(methylsulfanyl)-1,3-dithiane consists of a dithiane ring (a six-membered ring with two sulfur atoms) with a methylsulfanyl group (a methyl group attached to a sulfur atom) at position 2.
Functional groups
The dithiane ring and the methylsulfanyl group are the two main functional groups in 2-(methylsulfanyl)-1,3-dithiane.
Physical properties
The specific physical properties of 2-(methylsulfanyl)-1,3-dithiane are not provided in the material.
Uses
2-(methylsulfanyl)-1,3-dithiane is commonly used as a building block in organic synthesis, particularly in the preparation of heterocyclic compounds.
Protective group
The presence of the dithiane group makes 2-(methylsulfanyl)-1,3-dithiane a useful protective group for aldehydes and ketones, allowing for selective manipulation of these functional groups in complex molecule synthesis.
Reactivity
2-(methylsulfanyl)-1,3-dithiane can be used as a nucleophile in various reactions, making it a versatile reagent in organic chemistry.
Importance
2-(methylsulfanyl)-1,3-dithiane is an important and widely used compound in the field of chemical synthesis.
Check Digit Verification of cas no
The CAS Registry Mumber 14758-37-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,7,5 and 8 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 14758-37:
(7*1)+(6*4)+(5*7)+(4*5)+(3*8)+(2*3)+(1*7)=123
123 % 10 = 3
So 14758-37-3 is a valid CAS Registry Number.
14758-37-3Relevant articles and documents
A convenient high yield synthesis of functional methacrylates via dethioacetalization. Synthesis of methacrylate S,S-acetal derivatives as intermediates
Caye, Florence,Sindt, Michele,Mieloszynski, Jean-Luc,Paquer, Daniel
, p. 197 - 220 (2007/10/03)
We describe a selective and efficient synthesis of a whole new class of functional methacrylates starting from S,S-acetals. Carbonyl compounds were regenerated from corresponding S,S-acetaIs using mercury (II) salts. According to this method, methacrylic
Compositions of retinoids substituted with a dithiane ring, their use, and process for preparing the compounds
-
, (2008/06/13)
The invention relates to a stereospecific derivative of formula: STR1 in which R is hydrogen or a C 1 -C 4 thioalkyl. The invention also relates to the use of these compounds for the manufacture of stereospecific retinal or retinoic acid, as well as to a process for preparing the retinoids of formula (I). The invention finally relates to a cosmetic or pharmaceutcial composition which contains at least one compound of formula (I) in a suitable vehicle; the pharmaceutical composition according to the invention may be used for treating dermatological, rheumatic, respiratory or ophthalmological conditions.
Synthesis of E Functionalized Prenyl Orthothioesters
Solladie, Guy,Berl, Valerie
, p. 6329 - 6332 (2007/10/02)
A stereospecific route to (E)-3-2-methylpropenal 5 and to (E)-3-(4-methylthio-1,3-dithiane-2-yl)-2-methylpropenal 7 is described.
