1476-05-7

Basic information

• Product Name: 3-(2-Butenyloxy)-1-butene
• Synonyms: 3-(2-Butenyloxy)-1-butene
• CAS NO: 1476-05-7
• Molecular Formula: C8H14O
• Molecular Weight: 126.2
• Mol File: 1476-05-7.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-(2-Butenyloxy)-1-butene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-Butenyloxy)-1-butene(1476-05-7)
• EPA Substance Registry System: 3-(2-Butenyloxy)-1-butene(1476-05-7)

Safety Data

• Hazardous Substances Data: 1476-05-7(Hazardous Substances Data)

Usage

General Description

3-(2-Butenyloxy)-1-butene is an organic compound with the molecular formula C8H14O. It is a clear, colorless liquid with a slightly fruity odor. This chemical is often used as a solvent and a reagent in organic synthesis. It can undergo reactions such as addition, oxidation, and esterification, making it a versatile building block in the production of various compounds. It is important to handle 3-(2-Butenyloxy)-1-butene with care, as it is considered to be hazardous if not used properly.

Upstream product

• 598-32-3 2-hydroxy-3-butene 
• 4894-61-5 trans-but-2-enyl chloride 
• 76-03-9 trichloroacetic acid 
• 6117-91-5 (E/Z)-2-buten-1-ol 
• 504-61-0 (E)-but-2-enol 

Downstream Products

• 35194-31-1 6-octen-2-one 

Relevant articles and documents

1,2- and 1,5-Stereocontrols in 5-Hexenyl Radical Cyclizations: Cooperative or Antagonist Effect. Conformation Experimental Results with MM2 Calculations of Transition States

The cyclofunctionalization of 1,6-dienes 1 and 2 via the addition of tosyl radical allows the analysis of the combined effects of 1,2- and 1,5-stereocontrols on the outcome of 5-hexenyl radical cyclizations.MM2 calculations of the transition states agree quite well with the experimental selectivity, i.e., exclusive 1,2-trans control, and predominance of 1,5-cis over 1,5-trans relationship.The addition of TsBr to carbohydrate-derived epimeric dienes 3a and 3b shows that the stereochemistry of the newly formed C-C bond is controlled by the configuration of the C2 center of the radical. 1,5-trans or 1,5-cis selectivity can be achieved depending on the configuration of C2.