147731-05-3

Basic information

• Product Name: Phosphonic acid, [(S)-hydroxyphenylmethyl]-, bis(1-methylethyl) ester
• CAS NO: 147731-05-3
• Molecular Formula: C13H21O4P
• Molecular Weight: 272.281
• Mol File: 147731-05-3.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, [(S)-hydroxyphenylmethyl]-, bis(1-methylethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, [(S)-hydroxyphenylmethyl]-, bis(1-methylethyl) ester(147731-05-3)
• EPA Substance Registry System: Phosphonic acid, [(S)-hydroxyphenylmethyl]-, bis(1-methylethyl) ester(147731-05-3)

Safety Data

• Hazardous Substances Data: 147731-05-3(Hazardous Substances Data)

Upstream product

• 22950-57-8 diisopropyl benzoylphosphonate 
• 116-17-6 triisopropyl phosphite 
• 100-52-7 benzaldehyde 
• 1809-20-7 diisopropyl hydrogenphosphonate 
• 98-88-4 benzoyl chloride 
• 20386-43-0 (hydroxy-phenyl-methyl)-phosphonic acid diisopropyl ester 

Downstream Products

• 104944-23-2 (-)-(S)-1-phenyl-1-hydroxymethylphosphonic acid 
• 596113-54-1 (S)-diisopropyl 1-thiocyanatobenzylphosphonate 
• 596113-50-7 (S)-diisopropyl 1-(p-nitrobenzenesulfonyloxy)benzylphosphonate 

Relevant articles and documents

Asymmetric Synthesis of Chiral, Nonracemic Dialkyl-α-, β-, and γ-Hydroxyalkylphosphonates via a Catalyzed Enantioselective Catecholborane Reduction

A highly enantioselective synthesis of dialkyl α-hydroxyphosphonates achieved by a oxazaborolidine catalyzed reduction with catecholborane starting with α-ketophosphonates is described.Both α-aryl- and α-alkylketophosphonates were reduced using the (S)-en

1,1′-Dibenzyl-bis-(triazolyl)diphenylphosphine dioxide: A new efficient organocatalyst for silicon tetrachloride-mediated enantioselective Abramov-type phosphonylation of aldehydes with trialkyl phosphites

Asymmetric phosphonylation of aldehydes with trialkyl phosphites using a combination of SiCl4 and a novel 1,1′-dibenzyl-bis-(triazolyl)diphenylphosphine dioxide organocatalyst has been developed. This protocol provides the corresponding α-hydroxyphosphonates with a broad range of functional groups and substitution patterns in excellent yields and good selectivities.

Imidazolium ion tethered TsDPENs as efficient ligands for Iridium catalyzed asymmetric transfer hydrogenation of α-keto phosphonates in water

For the first time, an efficient method has been developed by the use of imidazolium ion tethered TsDPENs as efficient ligands for Iridium-catalyzed asymmetric transfer hydrogenation (ATH) of α-ketophosphonates in water. The reaction provided the desired