1477517-17-1

Basic information

• Product Name: C₁₉H₂₆BrN₂O₈PSi
• Synonyms: C₁₉H₂₆BrN₂O₈PSi
• CAS NO: 1477517-17-1
• Molecular Weight: 549.387
• Mol File: 1477517-17-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₉H₂₆BrN₂O₈PSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₉H₂₆BrN₂O₈PSi(1477517-17-1)
• EPA Substance Registry System: C₁₉H₂₆BrN₂O₈PSi(1477517-17-1)

Safety Data

• Hazardous Substances Data: 1477517-17-1(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 441351-33-3 3-(tert-butyldimethylsilyloxy)-5-hydroxybenzaldehyde 
• 1477517-16-0 C₁₃H₁₉BrO₃Si 
• 68641-49-6 bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride 
• 26153-38-8 3,5-dihydroxybenzaldehyde 

Relevant articles and documents

Efficient syntheses of korupensamines A, B and michellamine B by asymmetric Suzuki-Miyaura coupling reactions

Efficient asymmetric Suzuki-Miyaura coupling reactions are employed for the first time in total syntheses of chiral biaryl natural products korupensamine A and B in combination with an effective diastereoselective hydrogenation, allowing ultimately a concise and stereoselective synthesis of michellamine B. Chiral monophosphorus ligands L1-3 are effective for the syntheses of a series of functionalized chiral biaryls by asymmetric Suzuki-Miyaura coupling reactions in excellent yields and enantioselectivities (up to 99% ee). The presence of a polar-π interaction between the highly polarized BOP group and the extended π system of arylboronic acid coupling partner is believed to be important for the high enantioselectivity.