148114-02-7

Basic information

• Product Name: Butanedioic acid, 1-methylethenyl phenylmethyl ester
• CAS NO: 148114-02-7
• Molecular Formula: C14H16O4
• Molecular Weight: 248.279
• Mol File: 148114-02-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Butanedioic acid, 1-methylethenyl phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Butanedioic acid, 1-methylethenyl phenylmethyl ester(148114-02-7)
• EPA Substance Registry System: Butanedioic acid, 1-methylethenyl phenylmethyl ester(148114-02-7)

Safety Data

• Hazardous Substances Data: 148114-02-7(Hazardous Substances Data)

Upstream product

• 103-40-2 succinic acid monobenzyl ester 
• 41437-17-6 benzyl 4-chloro-4-oxobutanoate 
• 67-64-1 acetone 
• 108-22-5 Isopropenyl acetate 

Downstream Products

• 139155-58-1 succinic acid benzyl ester-phenyl ester 
• 148114-16-3 Succinic acid benzyl ester (R)-4,4-dimethyl-2-oxo-tetrahydro-furan-3-yl ester 
• 152035-97-7 benzyl 2-phenylethyl succinate 
• 148114-07-2 Succinic acid benzyl ester 1,1-dimethyl-2-phenyl-ethyl ester 

Relevant articles and documents

A Convenient Synthesis of Dicarboxylic Monoesters using Isopropenyl Esters: Synthesis of Oxaunomycin Derivatives

Reaction of various types of alcohols with a novel type of acylating agent, the isopropenyl esters 2a-e in the presence of a catalytic amount of conc. sulfuric acid or toluene-p-sulfonic acid followed by selective deprotection of the terminal ester gives the monoesters 5a-i in good yields.