148587-27-3Relevant articles and documents
Application of ene-like reactions of aldehydes with vinyl ethers: Facile assembly of benzazocenone intermediates for mitomycinoids
Ciufolini, Marco A.,Chen, Mingying,Lovett, Dennis P.,Deaton, Melissa V.
, p. 4355 - 4358 (1997)
Benzazocenone intermediates for mitomycinoids are now available in only sin steps. Key phases of this sequence include the ene-like reaction of 2-methoxypropene with a 2-azidophenylacetaldehyde and a novel heterocyclic ring formation/expansion reaction.
Yb(fod)3-promoted ene reaction of aldehydes with vinyl ethers
Deaton, Melissa V.,Ciufolini, Marco A.
, p. 2409 - 2412 (2007/10/02)
Catalytic amounts of Yb(fod)3 catalyze a bimolecular ene-like reaction between ordinary aldehydes and vinyl ethers, in which the oxygen functionality is located at the central carbon of an allylic system. These reactions proceed at room tempera
