148703-38-2

Basic information

• Product Name: 5-(benzylamino)-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose
• Synonyms: 5-(benzylamino)-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose
• CAS NO: 148703-38-2
• Molecular Weight: 279.336
• Mol File: 148703-38-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 5-(benzylamino)-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(benzylamino)-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose(148703-38-2)
• EPA Substance Registry System: 5-(benzylamino)-5-deoxy-1,2-O-isopropylidene-α-D-xylofuranose(148703-38-2)

Safety Data

• Hazardous Substances Data: 148703-38-2(Hazardous Substances Data)

Upstream product

• 532-20-7 α-D-xylofuranose 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 
• 34370-91-7 3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 117661-89-9 3-O-benzyl-1,2-O-isopropylidene-5-O-trifluoromethanesulphonyl-α-D-xylofuranose 
• 100-46-9 benzylamine 
• 6893-65-8 1,2-di-O-isopropylidene-5-O-tosyl-D-xylofuranose 

Downstream Products

• 4613-58-5 5-amino-5-deoxy-1,2-O-isopropylidene-a-D-xylofuranose 
• 1187322-20-8 C₂₄H₃₃N₃O₈ 
• 1426390-02-4 1-((5-((benzyl(((3aR,5R,6S,6aR)-6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl)amino)methyl)-1H-1,2,3-triazol-4-yl)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione 
• 196201-89-5 (4aR,5aR,8aR,8bS)-3-Benzyl-2-chloro-7,7-dimethyl-hexahydro-[1,3]dioxolo[4,5]furo[2,3-e][1,3,2]oxazaphosphinine 2-oxide 

Relevant articles and documents

Rh-Catalyzed asymmetric hydroaminomethylation of α-Substituted acrylamides: Application in the synthesis of RWAY

The successful rhodium-catalyzed asymmetric hydroformylation and hydroaminomethylation of α-substituted acrylamides is described using 1,3-phosphite-phosphoramidite ligands based on a sugar backbone. A broad scope of chiral aldehydes and amines were afforded in high yields and excellent enantioselectivities (up to 99%). Furthermore, the synthetic potential of this method is demonstrated by the single-step synthesis of the brain imaging molecule RWAY.

NOVEL DERIVATIVES OF ACYL CYANOPYRROLIDINES

A compound of formula (I) or a tautomeric form, regioisomer, stereoisomer, solvate, N-oxide or pharmaceutically acceptable salts thereof; wherein 'a' - is selected from the group consisting of substituted or unsubstituted heterocycloalkyl ring and substituted or unsubstituted carbohydrate moiety y is a member selected from -O-, -CO-, -S02-, aminoalkyl or formula (II) wherein, Rw is hydrogen, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heteroaryl; x is a member selected from -0-, -S-, -SO-, -S02-, CONR10, NR10CO and -NRd-, or x and y together represent a chemical bond; Z is selected from -CH-, -N-. t is an integer selected from O to 4; with the provisos that when 'a' is substituted or unsubstituted heterocycloalkyl ring then 't' is not O and when y = -CO-, x is not NRd.

Novel chiral xylofuranose-based phosphinooxathiane and phosphinooxazinane ligands for palladium-catalyzed asymmetric allylations

Novel chiral xylofuranose-based phosphinooxathiane and phosphinooxazinane ligands were found to provide high levels of enantioselectivity (up to 94% ee) in palladium-catalyzed asymmetric allylic alkylations and aminations.