148914-42-5

Basic information

• Product Name: 1,3,2-Benzodioxaborole, 2,2'-[1-(4-methoxyphenyl)-1,2-ethanediyl]bis-
• CAS NO: 148914-42-5
• Molecular Formula: C21H18B2O5
• Molecular Weight: 371.993
• Mol File: 148914-42-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 1,3,2-Benzodioxaborole, 2,2'-[1-(4-methoxyphenyl)-1,2-ethanediyl]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,2-Benzodioxaborole, 2,2'-[1-(4-methoxyphenyl)-1,2-ethanediyl]bis-(148914-42-5)
• EPA Substance Registry System: 1,3,2-Benzodioxaborole, 2,2'-[1-(4-methoxyphenyl)-1,2-ethanediyl]bis-(148914-42-5)

Safety Data

• Hazardous Substances Data: 148914-42-5(Hazardous Substances Data)

Upstream product

• 637-69-4 4-Methoxystyrene 
• 37737-62-5 tris(catecholato)diboron 
• 13826-27-2 2,2'-bis(1,3,2-benzodioxaborole) 
• 148914-43-6 (benzo-1,3,2-dioxoborolidyl)-(E)-2-(4-methoxyphenyl)ethene 
• 274-07-7 benzo[1,3,2]dioxaborole 
• 768-60-5 4-methoxyphenylacetylen 
• 14694-95-2 Wilkinson's catalyst 

Downstream Products

• 32345-64-5 1-(4-methoxyphenyl) ethane-1,2-diol 

Relevant articles and documents

Enantioselective preparation of a chiral-at-metal Cp*Ir(NHC) complex and its application in the catalytic diboration of olefins

The reaction of(S,S)-1,3-di(methylbenzyl)imidazolium chloride with [Cp*IrCl2]2 in the presence of NaOAc affords the diastereoselective formation of a Cp*Ir(NHC) complex with a chelating ligand coordinated through the carbene and the

Developing a Bench-Scale Green Diboration Reaction toward Industrial Application

We report a new methodology for the organocatalytic diboration reaction using inexpensive, sustainable, nontoxic, commercially available halogen salts. This is an educative manuscript for the transformation of laboratory scale reactions into a sustainable approach of appeal to industry.

Synthesis and structure of indenyl rhodium(I) complexes containing unsaturated phosphines: Catalyst precursors for alkene hydroboration

The indenyl compound (η5-C9H7)Rh(coe) 2 (1, coe = cis-cyclooctene) has been prepared as a thermally stable alternative to the diethylene derivative (η5-C9H 7)Rh(η2-H2CCH2)2. Compound 1 reacts with unsaturated phosphines Ph2PR (R = CHCH 2, 2; CH2CHCH2, 3; and CC-tert-Bu, 4) to give complexes of the type (η5-C9H7)Rh(Ph 2PR)2, where bonding occurs through the phosphorus atom. Addition of Ph2PCCPPh2 to 1 gave the dimer [(η5-C9H7)Rh(μ-Ph2PCCPPh 2)]2 (5). Solution and solid state data showed that these new phosphine complexes have only a moderate amount of distortion within the indenyl ring. These compounds were found to catalyse the hydroboration of vinylarenes and the first example of an internal hydroboration of diphenylvinylphosphine has been reported. The Royal Society of Chemistry 2009.