14908-27-1

Basic information

• Product Name: 2,5-dimethyl-4-hexen-2-ol
• Synonyms: 2,5-dimethyl-4-hexen-2-ol
• CAS NO: 14908-27-1
• Molecular Weight: 128.214
• Mol File: 14908-27-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,5-dimethyl-4-hexen-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-dimethyl-4-hexen-2-ol(14908-27-1)
• EPA Substance Registry System: 2,5-dimethyl-4-hexen-2-ol(14908-27-1)

Safety Data

• Hazardous Substances Data: 14908-27-1(Hazardous Substances Data)

Upstream product

• 110-03-2 2,5-dimethyl-2,5-hexanediol 

Downstream Products

• 15045-43-9 2,2,5,5-tetramethyltetrahydrofuran 
• 764-13-6 2,5-Dimethyl-2,4-hexadiene 
• 927-97-9 2,5-dimethyl-1,4-hexadiene 
• 90202-20-3 5-chloro-2,5-dimethyl-hex-2-ene 

Relevant articles and documents

2,2,5,5-Tetramethyltetrahydrofuran (TMTHF): A non-polar, non-peroxide forming ether replacement for hazardous hydrocarbon solvents

An inherently non-peroxide forming ether solvent, 2,2,5,5-tetramethyltetrahydrofuran (2,2,5,5-tetramethyloxolane), has been synthesized from readily available and potentially renewable feedstocks, and its solvation properties have been tested. Unlike traditional ethers, its absence of a proton at the alpha-position to the oxygen of the ether eliminates the potential to form hazardous peroxides. Additionally, this unusual structure leads to lower basicity compared with many traditional ethers, due to the concealment of the ethereal oxygen by four bulky methyl groups at the alpha-position. As such, this molecule exhibits similar solvent properties to common hydrocarbon solvents, particularly toluene. Its solvent properties have been proved by testing its performance in Fischer esterification, amidation and Grignard reactions. TMTHF's differences from traditional ethers is further demonstrated by its ability to produce high molecular weight radical-initiated polymers for use as pressure-sensitive adhesives.