149694-49-5

Basic information

• Product Name: methyl (3-methylfuran-2-yl)acetate
• CAS NO: 149694-49-5
• Molecular Weight: 154.166
• Mol File: 149694-49-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: methyl (3-methylfuran-2-yl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (3-methylfuran-2-yl)acetate(149694-49-5)
• EPA Substance Registry System: methyl (3-methylfuran-2-yl)acetate(149694-49-5)

Safety Data

• Hazardous Substances Data: 149694-49-5(Hazardous Substances Data)

Upstream product

• 197307-28-1 methyl 5-hydroxy-6-[(tert-butyldimethylsilyl)oxy]-4-methyl-2,3-hexadienoate 
• 117431-83-1 (Z)-tert-butyldimethyl((3-methylpent-2-en-4-yn-1-yl)oxy)silane 
• 6153-05-5 (Z)-3-methylpent-2-en-4-ynol 
• 197307-27-0 1-(2-ethynyl-2-methyloxirane)methanol tert-butyldimethylsilyl ether 
• 121693-79-6 (E)-tert-butyldimethyl-((3-methylpent-2-en-4-yn-1-yl)oxy)silane 
• 6153-06-6 (E)-3-methylpent-2-en-4-yn-1-ol 
• 30414-53-0 methyl propanoyl acetate 
• 367253-53-0 (E)-2-[(methoxycarbonyl)methylidene]-3-methyltetrahydrofuran 
• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 149694-48-4 (Z)-6-Methoxycarbonyloxy-4-methyl-hex-4-en-2-ynoic acid methyl ester 
• 149694-58-6 (Z)-6-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-4-en-2-ynoic acid methyl ester 

Downstream Products

• 15186-51-3 3-methyl-2-(3-methylbut-2-enyl)furan 

Relevant articles and documents

Efficient synthesis of furan-2-ylacetates, 7-(alkoxycarbonyl)benzofurans, and 7-(alkoxycarbonyl)-2,3-dihydrobenzofurans based on cyclization reactions of free and masked dianions: A "cyclization/dehydrogenation" strategy

A variety of furan-2-ylacetates have been prepared by dehydrogenation of monocyclic 2-alkylidene-tetrahydrofurans, which are readily available by cyclizations of open-chained 1,3-dicarbonyl dianions with 1-bromo-2- chloroethane. 5′H-[2,3′]Bifuranyl-2′-one

Efficient synthesis of functionalized furans and benzofurans based on a '[3+2] cyclization/oxidation' strategy

Functionalized furans and benzofurans were prepared by DDQ oxidation of 2-alkylidenetetrahydrofurans, which are readily available by one-pot cyclizations of 1,3-dicarbonyl dianions or 1,3-bis-silyl enol ethers.

Regioselective synthesis of functionalized furans by cyclization of 1,3-bis-silyl enol ethers with 1-chloro-2,2-dimethoxyethane

Cyclization of 1,3-bis-silyl enol ethers with 1-chloro-2,2-dimethoxyethane allowed an efficient, regio- and diastereo-selective synthesis of a variety of 2-alkylidene-4-methoxy-tetrahydrofurans. The TFA-mediated elimination of methanol resulted in the formation of functionalized furans. Simi larly, 2,3,3a,4,5,6-hexahydro-2,3-benzofurans were prepared and transformed into 4,5,6,7-tetrahydro-2,3-benzofurans by treatment with TFA Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.