149830-29-5

Basic information

• Product Name: Os(C₂₀H₈N₄((C₆H₄NHCO)2C₆H₃O)2(CH₂)2)(SC₆F₄H)
• CAS NO: 149830-29-5
• Molecular Weight: 1362.37
• Mol File: 149830-29-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Os(C₂₀H₈N₄((C₆H₄NHCO)2C₆H₃O)2(CH₂)2)(SC₆F₄H)(CAS DataBase Reference)
• NIST Chemistry Reference: Os(C₂₀H₈N₄((C₆H₄NHCO)2C₆H₃O)2(CH₂)2)(SC₆F₄H)(149830-29-5)
• EPA Substance Registry System: Os(C₂₀H₈N₄((C₆H₄NHCO)2C₆H₃O)2(CH₂)2)(SC₆F₄H)(149830-29-5)

Safety Data

• Hazardous Substances Data: 149830-29-5(Hazardous Substances Data)

Upstream product

• 769-40-4 2,3,5,6-tetrafluorothiophenol 

Downstream Products

• 149830-21-7 Os(C₂₀H₈N₄((C₆H₄NHCO)2C₆H₃O)2(CH₂)2)(OCH₃)(SC₆F₄H) 

Relevant articles and documents

Mercaptide complexes of osmium porphyrins. Structure of Os(TTP)(SC6F4H)2

Aryl mercaptans RSH (R = p-tolyl, C6F4H, C6F5,2,6-Me2C6H3) react with dioxoosmium(VI) porphyrins [porphyrin = meso-tetra-p-tolylporphyrin (TTP), octaethylporphyrin (OEP)] to give diamagnetic osmium(IV) derivatives which contain two mercaptide ligands. When sterically encumbered mercaptans and porphyrins are utilized, an Os(III) mercaptide complex results. Osmium(III) porphyrin mercaptide complexes can also be prepared either by pyridine-promoted reductive elimination of disulfide from Os(TTP)(SR)2 or by treating the metal-metal-bonded dimer [Os2(TTP)2]2+ with mercaptan/pyridine mixtures. The bis(mercaptido)osmium(IV) complex Os(TTP)-(SC6F4H)2 has been structurally characterized by X-ray diffraction [monoclinic C2/c, a = 23.750(5) ?, b = 16.625(4) ?, c = 15.049(3) ?, β = 92.05(2)°, Z = 4] and exhibits short metal-sulfur bond lengths.