149838-33-5

Basic information

• Product Name: 3-phenoxymethyl>-5-(((tert-butoxycarbonyl)amino)methyl)furan, tetra-tert-butyl ester
• Synonyms: 3-phenoxymethyl>-5-(((tert-butoxycarbonyl)amino)methyl)furan, tetra-tert-butyl ester
• CAS NO: 149838-33-5
• Molecular Weight: 1187.44
• Mol File: 149838-33-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-phenoxymethyl>-5-(((tert-butoxycarbonyl)amino)methyl)furan, tetra-tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-phenoxymethyl>-5-(((tert-butoxycarbonyl)amino)methyl)furan, tetra-tert-butyl ester(149838-33-5)
• EPA Substance Registry System: 3-phenoxymethyl>-5-(((tert-butoxycarbonyl)amino)methyl)furan, tetra-tert-butyl ester(149838-33-5)

Safety Data

• Hazardous Substances Data: 149838-33-5(Hazardous Substances Data)

Upstream product

• 149838-27-7 3--5-(((tert-butoxycarbonyl)amino)methyl)furan 
• 149838-31-3 N-(tert-butoxycarbonyl)-γ-L-glutamyl-γ-L-glutamyl-γ-L-glutamyl-L-glutamic acid, α,α',α'',α'''-tetra-tert-butyl γ-methyl pentaester 
• 149838-28-8 N-(tert-butoxycarbonyl)-γ-L-glutamyl-L-glutamic acid, α,α'-di-tert-butyl γ-methyl triester 
• 149838-29-9 (S)-5-(tert-butoxy)-4-((S)-5-(tert-butoxy)-4-((tert-butoxycarbonyl)amino)-5-oxopentanamido)-5-oxopentanoic acid 
• 149838-26-6 3-phenoxymethyl>-5-(((tert-butyloxycarbonyl)amino)methyl)furan 
• 149838-30-2 N-γ-L-glutamyl-L-glutamic acid, α,α'-di-tert-butyl γ-methyl triester 
• 24277-38-1 (S)-(-)-1-tert-butyl-5-methyl-<(2-tert-butoxycarbonyl)amino>pentanedioate 
• 149838-25-5 p-<β-(((trimethylsilylethoxy)carbonyl)amino)ethyl>phenol 
• 24277-39-2 N-tert-butoxycarbonyl glutamic acid tert-butyl ester 
• 5891-45-2 (S)-2-(benzyloxycarbonylamino)pentanedioic acid tert-butyl ester 
• 79640-72-5 L-glutamic acid 1-tert-butyl ester 5-methyl ester 
• 51-67-2 tyrosamine 
• 23736-78-9 N-(benzyloxycarbonyl)-γ-L-glutamyl-L-glutamic acid, α,α'-di-tert-butyl γ-methyl triester 
• 57732-63-5 1-tert-butyl 5-methyl (2S)-2-{[(benzyloxy)carbonyl]amino}pentanedioate 

Relevant articles and documents

Total synthesis of the methanogenic cofactors methanofuran and methanofuran b

Methanofuran, 3-[p-((N-(N″-((4R,5S)- or (4S,5A)-4,5,7-tricarboxyheptanoyl)-γL-glutamyl-γ-L-glutamyl)-β- amino)ethyl]phenoxymethyl}-5-(aminomethyl)furan, and methanofuran b, 3-{p-[(N-(-γ-L-glutamyl-γ-L-glutamyl-γ-L-glutamyl-γ-L- glutamyl)-β-amino)ethyl]phenoxymethyl}-5-(aminomethyl)furan, are the first cofactors involved in the conversion of carbon dioxide to methane by the methanogenic bacteria Methanobacterium thermoautotrophicum and Methanosarcina barkeri, respectively. These two cofactors have now been synthesized, starting from glutamic acid, dimethyl glutarate, methyl 5-formyl-3-furoate, and tyramine. The synthetic compounds give the same NMR and mass spectra and biological activities as the natural cofactors.