150675-33-5

Basic information

• Product Name: tricarbonyl(1-phenylbuta-1,3-diene)iron⁽⁰⁾
• CAS NO: 150675-33-5
• Molecular Weight: 270.068
• Mol File: 150675-33-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tricarbonyl(1-phenylbuta-1,3-diene)iron⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: tricarbonyl(1-phenylbuta-1,3-diene)iron⁽⁰⁾(150675-33-5)
• EPA Substance Registry System: tricarbonyl(1-phenylbuta-1,3-diene)iron⁽⁰⁾(150675-33-5)

Safety Data

• Hazardous Substances Data: 150675-33-5(Hazardous Substances Data)

Upstream product

• 15321-51-4 diiron nonacarbonyl 
• 1515-78-2 buta-1,3-dien-1-ylbenzene 
• 624-48-6 dimethyl cis-but-2-ene-1,4-dioate 
• 38720-22-8 (benzalacetone)Fe(CO)3 
• 29817-09-2 1-methylene-2-phenylcyclopropane 

Relevant articles and documents

Synthesis and oxidation of the decarbonylated adducts generated from alkenes and tricarbonyl(vinylketene)iron(o) complexes

The tricarbonylvinyl(vinylketene)iron(o) complex 6 reacted with dimetyl maleate, dimethyl fumarate, (E)-methyl 4-oxopent-2-enoate and (E)-ethyl 4,4,4-trifluorobut-2-enoate to give decarbonylated adducts 7-10 respectively.An X-ray crystal structure analysis of the adduct 7, formed from the complex 6, and dimethyl maleate, and a mechanistic explanation for the adducts are presented.Oxidation of the adducts 7-10 using (NH4)2Ce(NO3)6 gave a range of organic products including the tetrasubstituted cyclopropanes 20 and 23-25, the cyclobutane-1,2-dione 22, the trisubstituted lactone 21 and the α,β-unsaturated ketone 26.