150716-79-3Relevant articles and documents
Rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions
Orlando, John J.,Tyndall, Geoffrey S.,Apel, Eric C.,Riemer, Daniel D.,Paulson, Suzanne E.
, p. 334 - 353 (2003)
The rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions were studied. It was observed the product yielded from both trans-2-butene and 1-butene were found to be oxygen dependent. The results showed that the variation of the product yielded with O2 in the case of 1-butene resulted from competitive reaction pathways for the two β-chlorobutoxy radicals involved in the oxidation.