151193-35-0

Basic information

• Product Name: (S)-3-Hydroxy-2-{[1-(4-methoxy-phenyl)-meth-(E)-ylidene]-amino}-propionic acid methyl ester
• CAS NO: 151193-35-0
• Molecular Weight: 237.255
• Mol File: 151193-35-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-3-Hydroxy-2-{[1-(4-methoxy-phenyl)-meth-(E)-ylidene]-amino}-propionic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-Hydroxy-2-{[1-(4-methoxy-phenyl)-meth-(E)-ylidene]-amino}-propionic acid methyl ester(151193-35-0)
• EPA Substance Registry System: (S)-3-Hydroxy-2-{[1-(4-methoxy-phenyl)-meth-(E)-ylidene]-amino}-propionic acid methyl ester(151193-35-0)

Safety Data

• Hazardous Substances Data: 151193-35-0(Hazardous Substances Data)

Upstream product

• 2788-84-3 (S)-serine methyl ester 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 231291-91-1 (E)-(S)-1-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzylamino)-octadec-4-en-3-one 
• 231291-93-3 ((E)-(S)-1-Hydroxymethyl-2-oxo-heptadec-3-enyl)-(4-methoxy-benzyl)-carbamic acid tert-butyl ester 
• 231291-87-5 (E)-1-[(S)-3-(4-Methoxy-benzyl)-2,2-dimethyl-oxazolidin-4-yl]-hexadec-2-en-1-one 
• 231291-81-9 (E)-(2S,3S)-2-(4-Methoxy-benzylamino)-octadec-4-ene-1,3-diol 
• 231291-79-5 (E)-(2S,3R)-2-(4-Methoxy-benzylamino)-octadec-4-ene-1,3-diol 
• 231291-85-3 {2-[(S)-3-(4-Methoxy-benzyl)-2,2-dimethyl-oxazolidin-4-yl]-2-oxo-ethyl}-phosphonic acid dimethyl ester 
• 231291-83-1 (S)-3-(4-Methoxy-benzyl)-2,2-dimethyl-oxazolidine-4-carboxylic acid methyl ester 
• 936362-63-9 N-(p-methoxybenzyl)-L-serine methyl ester 

Relevant articles and documents

Stereoselective synthesis of β-amino alcohols: Practical preparation of all four stereomers of N-PMB-protected sphingosine from L- and D-serine

Serine was efficiently converted to the N-p-methoxybenzyl (PMB) protected α'-amino enone derivative 6, which was reduced with Zn(BH4)2 to the corresponding anti-β-amino alcohol in >96% de. On the other hand, N- PMB-N-Boc-protected α'-amino enone derivative 8 was reduced by NaBH4 to syn-product with a diastereoselectivity of ca. 90%.