1514894-42-8

Basic information

• Product Name: (4-(((2R,3R)-3-methyl-3-((R)-3-((2S,5S)-2-methyl-5-(2-((triethylsilyl)oxy)propan-2-yl)tetrahydrofuran-2-yl)-3-((triethylsilyl)oxy)propyl)oxiran-2-yl)methyl)-2-nitro-1H-pyrrol-1-yl)methyl benzoate
• Synonyms: (4-(((2R,3R)-3-methyl-3-((R)-3-((2S,5S)-2-methyl-5-(2-((triethylsilyl)oxy)propan-2-yl)tetrahydrofuran-2-yl)-3-((triethylsilyl)oxy)propyl)oxiran-2-yl)methyl)-2-nitro-1H-pyrrol-1-yl)methyl benzoate
• CAS NO: 1514894-42-8
• Molecular Weight: 745.117
• Mol File: 1514894-42-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4-(((2R,3R)-3-methyl-3-((R)-3-((2S,5S)-2-methyl-5-(2-((triethylsilyl)oxy)propan-2-yl)tetrahydrofuran-2-yl)-3-((triethylsilyl)oxy)propyl)oxiran-2-yl)methyl)-2-nitro-1H-pyrrol-1-yl)methyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (4-(((2R,3R)-3-methyl-3-((R)-3-((2S,5S)-2-methyl-5-(2-((triethylsilyl)oxy)propan-2-yl)tetrahydrofuran-2-yl)-3-((triethylsilyl)oxy)propyl)oxiran-2-yl)methyl)-2-nitro-1H-pyrrol-1-yl)methyl benzoate(1514894-42-8)
• EPA Substance Registry System: (4-(((2R,3R)-3-methyl-3-((R)-3-((2S,5S)-2-methyl-5-(2-((triethylsilyl)oxy)propan-2-yl)tetrahydrofuran-2-yl)-3-((triethylsilyl)oxy)propyl)oxiran-2-yl)methyl)-2-nitro-1H-pyrrol-1-yl)methyl benzoate(1514894-42-8)

Safety Data

• Hazardous Substances Data: 1514894-42-8(Hazardous Substances Data)

Upstream product

• 5335-05-7 chloromethyl benzoate 
• 106-24-1 Geraniol 
• 98-88-4 benzoyl chloride 
• 1514894-29-1 5-(((5R)-5-((2S,5S)-2-methyl-5-(2-((triethylsilyl)oxy)propan-2-yl)tetrahydrofuran-2-yl)-5-((triethylsilyl)oxy)pentan-2-yl)thio)-1-phenyl-1H-tetrazole 
• 1514894-28-0 (5R)-5-((2S,5S)-2-methyl-5-(2-((triethylsilyl)oxy)propan-2-yl)tetrahydrofuran-2-yl)-5-((triethylsilyl)oxy)pentan-2-ol 
• 1514894-26-8 triethyl((2-((2S,5S)-5-methyl-5-((R)-1-((triethylsilyl)oxy)pent-4-en-1-yl)tetrahydrofuran-2-yl)propan-2-yl)oxy)silane 
• 1514894-25-7 (R)-1-((2S,5S)-2-methyl-5-(2-((triethylsilyl)oxy)propan-2-yl)tetrahydrofuran-2-yl)pent-4-en-1-ol 
• 1514894-23-5 triethyl ((2-((2S,5S)-5-methyl-5-((R)-oxiran-2-yl)tetrahydrofuran-2-yl)propan-2-yl)oxy)silane 
• 1514894-22-4 (R)-2-hydroxy-2-((2S,5S)-5-(2-hydroxypropan-2-yl)-2-methyltetrahydrofuran-2-yl)ethyl methanesulfonate 
• 61573-90-8 ((2R,3R)-3-methyl-3-(4-methylpent-3-en-1-yl)oxiran-2-yl)methyl methanesulfonate 
• 50727-94-1 (2R,3R)-3-methyl-3-(4-methyl-3-pentenyl)oxiranemethanol 
• 1514894-19-9 (2-nitro-4-(2-oxoethyl)-1H-pyrrol-1-yl)methyl benzoate 
• 1514894-16-6 1-benzoyloxymethyl-2-nitro-4vinyl-pyrrole 
• 1514894-12-2 1-benzoyloxymethyl-2-nitro-4-iodopyrrole 

Relevant articles and documents

Total synthesis of heronapyrrole C

A flexible total synthesis of the 2-nitropyrrole-derived marine natural product, (+)-heronapyrrole C, is reported. The approach is based on regioselective access to key building blocks containing the rare 4-substituted 2-nitropyrrole motif. Sharpless asymmetric epoxidation and dihydroxylation and a Shi epoxidation were used to introduce the five stereogenic centers of the bis-THF-diol side chain. The N-benzoyloxymethyl (Boz) protecting group was crucial for functionalization of the 2-nitropyrrole moiety and enabling final deprotection under mild conditions.