151526-76-0

Basic information

• Product Name: (2S,3S)-2,3-dimethylaziridine
• Synonyms: (2S,3S)-2,3-dimethylaziridine
• CAS NO: 151526-76-0
• Molecular Weight: 71.1222
• Mol File: 151526-76-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3S)-2,3-dimethylaziridine(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-2,3-dimethylaziridine(151526-76-0)
• EPA Substance Registry System: (2S,3S)-2,3-dimethylaziridine(151526-76-0)

Safety Data

• Hazardous Substances Data: 151526-76-0(Hazardous Substances Data)

Upstream product

• 624-64-6 trans-2-Butene 

Downstream Products

• 151413-98-8 (2S,3S)-1-bromo-2,3-dimethylaziridine 

Relevant articles and documents

The Reactions of Singlet NH Radicals with C4 Olefins in the Liquid Phase

The reactions of NH radicals with C4 olefins, trans- and cis-2-butenes, 1-butene, and isobutene, were investigated by the photolysis of hydrogen azide in the liquid olefin at 0 deg C and at the temperature of Dry Ice-methanol.Except for nitrogen and ammonia, amines and aziridines were found to be formed in good yield. 2-Butene-1-amine and trans-2,3-dimethylaziridine from trans-2-butene, 2-butene-1-amine and cis-2,3-dimethylaziridine from cis-2-butene, 3-butene-1- and 2-amines and 2-ethylaziridine from 1-butene, and 2-methyl-2-propene-1-amine and 2,2-dimethylaziridine from isobutene.These product formations were successfully explained by the insertion into the C-H bond and the addition to the double bond of olefin by the singlet NH radicals.In the case of 2-butene, no isomerized aziridine formation was observed.This result suggested that the triplet NH radicals rarely add to the double bond of olefin.