15154-50-4Relevant articles and documents
Cluster synthesis by photolysis of R3PAuN3. Crystal structure of OH and NO3
Beuter, Georg,Straehle, Joachim
, p. 67 - 78 (1989)
Photolysis of R3PAuN3 (1) results in a reductive elimination of the azide group yielding R3PAu0 moieties which then combine to form Au clusters.In the presence of metal carbonyls heterometalic clusters are obtained.In the case of Mo(CO)6 the ca
LXVII. Reactions of some Fe-Ir clusters. Crystal structures of Fe2Ir(μ-H)(μ3-CCHPh)(CO)8(PPh3) and Au2Fe2Ir(μ4-C2Ph)(CO)7(PPh3)3
Bruce, Michael I.,Koutsantonis, George A.,Tiekink, Edward R. T.
, p. 77 - 94 (1991)
Isomeric hydrido-vinylidene and -alkyne complexes Fe2Ir(μ-H)(μ3-X)(CO)8(PPh3) (X = CCHPh, H2CPh) were obtained from Fe2Ir(μ3-C2Ph)(CO)8(PPh3) and H2 or H-/H+.The X-ray structure of the vinylidene complex is repo
Syntheses of gold-manganese and gold-rhenium clusters, and + (M = Mn, Re), and the crystal structure of BF4
Nicholson, Brian K.,Bruce, Michael I.,Shawkataly, Omar bin,Tiekink, Edward R. T.
, p. 411 - 418 (2007/10/02)
The specific additions of one, three or four Ph3PAu groups to - (M = Mn, Re) are described.Thus - in THF reacts with BF4 to give BF4.An X-ray crystal structure of the M = Mn example shows the cation to have a trigonal bipyramidal Au4Mn core with the Mn in an equatorial site.The previously known neutral (Ph3PAu)3M(CO)4 clusters are formed by addition of two Ph3PAu groups, using the mixed reagent BF4/, to Ph3PAuM(CO)5, which itself is readily prepared from - and Ph3PAuCl.
