152270-19-4Relevant articles and documents
COMPOUND, DETECTION MATERIAL AND DETECTION METHOD OF SUGAR COMPOUND USING THE SAME
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, (2020/02/22)
PROBLEM TO BE SOLVED: To provide a novel compound suitable for detection of a sugar compound, and detection means of the sugar compound using the same. SOLUTION: There is provided a compound represented by the general formula (A1) or (B1). Ar1 is a substituent and/or an aromatic ring which may have a hetero group in a ring; each Ar2 each independently is an aromatic ring which may have a substituent, Ar3 is an aromatic ring which has at least one -B(OH)2 and may have a substituent; R1 is H or a C1 to 20 alkyl group or an alkyloxy group which may have a hetero atom in a middle of a carbon chain; n is an integer of 1 to 5; and a bond represented by a combination of a double bond and a dash line each independently is a double bond or a triple bond. SELECTED DRAWING: None COPYRIGHT: (C)2020,JPOandINPIT
Eumelanin-inspired core derived from vanillin: A new building block for organic semiconductors
Selvaraju, Subhashini,Sachinthani, K. A. Niradha,Hopson, RaiAnna A.,McFarland, Frederick M.,Guo, Song,Rheingold, Arnold L.,Nelson, Toby L.
, p. 2957 - 2959 (2015/02/19)
An eumelanin-inspired core derived from the natural product, vanillin (vanilla bean extract) was utilized for the synthesis of eumelanin-inspired small molecules and polymer via Sonogashira cross coupling. The materials demonstrate that the methyl 4,7-dibromo-5,6-dimethoxy-N-methyl-1H-indole-2-carboxylate core can serve as a new building block for organic semiconductors.
Molecular spoked wheels: Synthesis and self-assembly studies on rigid nanoscale 2D objects
Aggarwal, A. Vikas,Jester, Stefan-S.,Taheri, Sara Mehdizadeh,Foerster, Stephan,Hoeger, Sigurd
, p. 4480 - 4495 (2013/05/23)
We present the efficient synthesis of a new molecular spoked-wheel structure (MSW-3). Two derivatives with diameters of approximately 4 nm have been prepared. By highlighting the importance of pseudo-high-dilution conditions during cyclization, we were able to access the compounds on a several hundred milligram scale. In addition to the standard characterization (NMR spectroscopy, MS), we describe a detailed investigation of the optical properties of the fluorescent MSWs by comparison with appropriate model chromophores. Furthermore, a comprehensive study of the structure in solution by means of light- and X-ray scattering experiments has been conducted. Scanning tunneling microscopy (STM) revealed the two-dimensional organization of the molecules on highly oriented pyrolytic graphite and emphasized the spoked-wheel structure. The diameter of these molecules measured by small-angle X-ray scattering is in very good agreement with that obtained from STM and matches the results of molecular modeling. This confirms the rigidifying effect of the spokes, which results in highly shape-persistent nanometer-sized oblate organic compounds. Copyright