152715-78-1

Basic information

• Product Name: 7-methyl-1-trityloxy-6-octen-2-ol
• Synonyms: 7-methyl-1-trityloxy-6-octen-2-ol
• CAS NO: 152715-78-1
• Molecular Weight: 400.561
• Mol File: 152715-78-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 7-methyl-1-trityloxy-6-octen-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 7-methyl-1-trityloxy-6-octen-2-ol(152715-78-1)
• EPA Substance Registry System: 7-methyl-1-trityloxy-6-octen-2-ol(152715-78-1)

Safety Data

• Hazardous Substances Data: 152715-78-1(Hazardous Substances Data)

Upstream product

• 76-83-5 trityl chloride 
• 65291-30-7 trityl glycidyl ether 
• 37586-57-5 4-methyl-3-pentenylmagnesium bromide 

Downstream Products

• 152715-79-2 7-methyl-1-trityloxy-6-octen-2-one 

Relevant articles and documents

Insight into Rh(I)-catalyzed cyclization of 6-octen-1-als with a chiral protecting group

Rh(I)(Wilkinson)[ClRh(PPh3)3]-catalyzed cyclization of 6-octen-als with a chiral protecting group at the C2-position afforded only cis-cyclohexanol derivatives, and in the case of C4-position yielded a mixture of cis and trans cyclohexanol. These findings were remakably different from the case of the C3-position, in which the trans cyclohexanol derivative was obtained. Wilkinson's complex acts as [ClRh(PPh3)3] a Lewis acid, and this bulkier Lewis acid affords higher diastereoselectivity. Rh(I)-catalyzed cyclization of 6-octen-1-al derivatives is not affected by chiral ligands.