153035-39-3

Basic information

• Product Name: 5-Hexenamide, N-phenyl-
• CAS NO: 153035-39-3
• Molecular Formula: C12H15NO
• Molecular Weight: 189.257
• Mol File: 153035-39-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 5-Hexenamide, N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexenamide, N-phenyl-(153035-39-3)
• EPA Substance Registry System: 5-Hexenamide, N-phenyl-(153035-39-3)

Safety Data

• Hazardous Substances Data: 153035-39-3(Hazardous Substances Data)

Upstream product

• 153035-24-6 N-Phenyl-2-(trimethylsilyl)propenamide 
• 103-71-9 phenyl isocyanate 
• 1577-22-6 5-hexenoic acid 
• 62-53-3 aniline 
• 1028281-08-4 2-Trimethylsilanyl-hex-5-enoic acid phenylamide 
• 36394-07-7 5-hexenoyl chloride 

Downstream Products

• 929278-37-5 methyl 2-phenyl-2-[N-phenyl-N-(hex-5'-enoyl)amino]acetate 
• 926310-14-7 6-azido-hexanoic acid phenylamide 
• 1454693-08-3 N-(6-{[(4-nitrophenyl)sulfanyl]-methyl}tetrahydro-2H-pyran-2-ylidene)anilinium perchlorate 

Relevant articles and documents

Low-Valent Tungsten Catalysis Enables Site-Selective Isomerization-Hydroboration of Unactivated Alkenes

A tungsten-catalyzed hydroboration of unactivated alkenes at distal C(sp3)-H bonds aided by native directing groups is described herein. The method is characterized by its simplicity, exquisite regio- and chemoselectivity, and wide substrate scope, offering a complementary site-selectivity pattern to other metal-catalyzed borylation reactions and chain-walking protocols.

Anti-Markovnikov Hydroazidation of Alkenes by Visible-Light Photoredox Catalysis

The anti-Markovnikov hydroazidation of alkenes has been accomplished under visible-light irradiation by using [Ir(dF(CF3)ppy)2(dtbbpy)]PF6 as the photocatalyst and trimethylsilyl azide as the azidating agent. The reactions were greatly facilitated by water, the beneficial effect of which can be attributed to its participation in the reaction as the hydrogen donor, as indicated by deuterium isotope experiments. The reactions proceed under solvent free conditions in the presence of water. 4-Dimethylaminopyridine also exhibited a beneficial effect on the reactions. The present method enabled hydroazidation of several types of unactivated alkenes with good yields and high regioselectivity.

Effect of substitution on the intramolecular 1,3-dipolar cycloaddition of alkene tethered muenchnones

(Chemical Equation Presented) A sequence of chemoselective activation of N-acylaminoacids, muenchnone generation, intramolecular 1,3-dipolar cycloaddition, and ring opening efficiently generated functionalized polycyclic structures such as cyclopenta[b]py