15376-84-8Relevant articles and documents
Dichlorodinickel(I) complexes with μ2-CO or μ2-CS bridges and trimethylphosphane ligands: Homologous composition, but different frameworks
Klein, Hans-Friedrich,Schmidt, Andreas,Floerke, Ulrich,Haupt, Hans-Juergen
, p. 2385 - 2387 (1998)
High ligand mobility is shown by the coordinatively unsaturated nickel(I) compound 1 with a short Ni-Ni distance and an asymmetric CO bridge. The thio homologue 2 contains the novel (thiocarbonyl)trimethylphosphorane bridging ligand, which sits like a 'stork's nest' on top of the roof-shaped dinuclear complex. In contrast to 1, complex 2 does not show fluctional behavior and can be methylated without decomposition. X = Cl, Me.
Synthesis and X-ray Structure of the Nickelabenzocyclopentene Complex . Reactivity Toward Simple, Unsaturated Molecules and the Crystal and Molecular Structure of the Cyclic Carboxylate
Carmona, Ernesto,Gutierrez-Puebla, Enrique,Marin, Jose M.,Monge, Angeles,Paneque, Margarita,at al.
, p. 2883 - 2891 (2007/10/02)
Facile cyclometalation to the nickelacyclopentene complex (1) occurs upon alkylation of NiCl2(PMe3)2 with 2 equiv of Mg(CH2CMe2Ph)Cl, in the presence of traces I(1-).Compound 1 has been fully characterized by spectroscopic and X-ray studies.Its
Carmona, Ernesto,Gutierrez-Puebla, Enrique,Marin, Jose M.,Monge, Angeles,Paneque, Margarita,at al.
, p. 2883 - 2891 (2007/10/02)
Facile cyclometalation to the nickelacyclopentene complex (1) occurs upon alkylation of NiCl2(PMe3)2 with 2 equiv of Mg(CH2CMe2Ph)Cl, in the presence of traces I(1-).Compound 1 has been fully characterized by spectroscopic and X-ray studies.Its
