1537901-02-2Relevant articles and documents
Formation of the tetranuclear, tetrakis-terminal-imido Mn4 IV(NtBu)8 cubane cluster by four-electron reductive elimination of tBuNNtBu. the role of the s-block ion in stabilization of high-oxidation state intermediates
Vaddypally, Shivaiah,Kondaveeti, Sandeep K.,Roudebush, John H.,Cava, Robert J.,Zdilla, Michael J.
, p. 1061 - 1063 (2014)
Mn4IV(μ3-NtBu) 4(NtBu)4 is obtained from a previously reported asymmetric MnIV/V-Li-(NR)(N) cluster by the removal of Li from the starting cluster by ion metathesis, which triggers reductive elimination of azo-tert-butane to give a tetranuclear heterocubane cluster.