153947-47-8

Basic information

• Product Name: 6-O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose
• Synonyms: 6-O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose
• CAS NO: 153947-47-8
• Molecular Weight: 734.841
• Mol File: 153947-47-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 6-O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 6-O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose(153947-47-8)
• EPA Substance Registry System: 6-O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose(153947-47-8)

Safety Data

• Hazardous Substances Data: 153947-47-8(Hazardous Substances Data)

Upstream product

• 10534-59-5 tetrabutylammonium acetate 
• 213028-97-8 6-O-(3,4,6-tri-O-benzyl-2-O-trifluoromethanesulfonyl-β-D-glucopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 
• 53270-12-5 1,2-O-(1-ethoxyethylene) 3,4,6-tri-O-benzyl-1-thio-α-D-glucopyranose 
• 74372-90-0 3,4,6-tri-O-benzyl-D-glucal epoxide 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 108869-64-3 3,4,6-tri-O-benzyl-2-O-acetyl-α-D-glucosyl trichloroimidate 
• 100-39-0 benzyl bromide 
• 3254-17-9 3,4,6-tri-O-acetyl-1,2-O-(1-ethoxyethylidene)-α-D-glucopyranose 
• 4064-06-6 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 
• 40246-33-1 3,4,6-tri-O-benzyl-β-D-glucopyranoside-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside 
• 51532-76-4 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranosyl(1→6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 
• 40246-34-2 (2R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-((3aR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-ylmethoxy)-dihydro-pyran-3-one 
• 108-24-7 acetic anhydride 
• 112330-11-7 (3,4,6-tri-O-benzyI-β-D-mannopyranosyl)-(1→6)-1,2,3,4-di-O-isoprpopylidene-α-D-galactopyranoside 

Downstream Products

• 112330-11-7 (3,4,6-tri-O-benzyI-β-D-mannopyranosyl)-(1→6)-1,2,3,4-di-O-isoprpopylidene-α-D-galactopyranoside 

Relevant articles and documents

Protecting group and solvent effects in electrochemical glycosylation

An investigation is undertaken into the roles of protecting groups and the solvent in the electrochemical-mediated glycosylation of manno thioglycosides. Herein notable differences are observed between electrochemical and chemical glycosylation. Georg Thi

Expedient stereospecific synthesis of β-mannosides from a glucose- derived 1,2-orthoester

A new, stereospecific synthesis of β-mannosides from glucose-derived 1,2-orthoester has been developed using a simple four-step procedure. For the synthesis of β-D-Man-(1→6)-D-Gal, a 6-OH free galactose derivative was glycosylated with the orthoester to yield β-D-Glc-(1→6)-D-Gal; the Glc unit of which was epimerized into the β-mannoside in good yield.

Route from Glycals to Mannose β-Glycosides

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