153996-22-6Relevant articles and documents
The use of 1,2-trans-cyclohexanediol as an efficient chiral auxiliary for the asymmetric cyclopropanation of allylic ethers
Charette,Marcoux
, p. 7157 - 7160 (2007/10/02)
A new and simple chiral auxiliary derived from optically pure 1,2-trans-cyclohexanediol was developed for the asymmetric Simmons-Smith cyclopropanation of substituted allylic alcohols. Excellent yields and diastereoselectivities were obtained with a variety of olefins.