15429-31-9

Basic information

• Product Name: 1-phenyl-3-methoxy-2,2-dimethylpropanone
• Synonyms: 1-phenyl-3-methoxy-2,2-dimethylpropanone
• CAS NO: 15429-31-9
• Molecular Weight: 192.258
• Mol File: 15429-31-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-phenyl-3-methoxy-2,2-dimethylpropanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-3-methoxy-2,2-dimethylpropanone(15429-31-9)
• EPA Substance Registry System: 1-phenyl-3-methoxy-2,2-dimethylpropanone(15429-31-9)

Safety Data

• Hazardous Substances Data: 15429-31-9(Hazardous Substances Data)

Upstream product

• 107-30-2 chloromethyl methyl ether 
• 611-70-1 phenyl isopropyl ketone 
• 15429-30-8 3-bromo-2,2-dimethyl-1-phenyl-propan-1-one 
• 124-41-4 sodium methylate 

Downstream Products

• 76002-15-8 (E)-1-methoxy-2,2-dimethyl-3-phenylhex-4-en-3-ol 
• 76002-13-6 6-methoxy-5,5-dimethyl-4-phenylhexa-2,3-diene 
• 76002-11-4 1-methoxy-2,2-dimethyl-3-phenylhex-4-yn-3-ol 

Relevant articles and documents

THIONE PHOTOCHEMISTRY. DUAL PATHWAYS IN ARALKYL THIONE CYCLIZATIONS

It is shown that aralkyl thiones, which posses an oxygen atom at the δ position in the side chain, can therefore not undergo the preferred δ insertion, and insert at the γ and ε positions.Although ε insertion occurs only from the 1(Π,Π*) state, γ abstraction ( followed by cyclization or cleavage ) occurs from both 1(Π,Π*) and 3(n,Π*) states.The quantum yields of photocyclization of 2c, 2d, and 2g change little with solvent polarity, which suggest that a thione-ether charge transfer interaction contributes little to the cyclization.Fluorescence and product quenching studies are reported which support this.