154479-68-2

Basic information

• Product Name: 1-(3-nitro-phenyl)-pentane-1,4-dione
• Synonyms: 1-(3-nitro-phenyl)-pentane-1,4-dione
• CAS NO: 154479-68-2
• Molecular Weight: 221.213
• Mol File: 154479-68-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(3-nitro-phenyl)-pentane-1,4-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3-nitro-phenyl)-pentane-1,4-dione(154479-68-2)
• EPA Substance Registry System: 1-(3-nitro-phenyl)-pentane-1,4-dione(154479-68-2)

Safety Data

• Hazardous Substances Data: 154479-68-2(Hazardous Substances Data)

Upstream product

• 4996-15-0 3-(3-nitrophenyl)propynoic acid 
• 67-64-1 acetone 
• 99-61-6 3-nitro-benzaldehyde 
• 78-94-4 methyl vinyl ketone 
• 2227-64-7 3'-nitro-2-bromoacetophenone 
• 123-54-6 acetylacetone 

Downstream Products

• 154479-76-2 2-(3-Azido-phenyl)-5-methyl-1-phenyl-1H-pyrrole 
• 154479-72-8 3-(5-Methyl-1-phenyl-1H-pyrrol-2-yl)-phenylamine 
• 154479-69-3 2-methyl-5-(3-nitrophenyl)-1-phenyl-1H-pyrrole 

Relevant articles and documents

Copper-Catalyzed Decarboxylative Oxyalkylation of Alkynyl Carboxylic Acids: Synthesis of ?-Diketones and ?-Ketonitriles

A novel copper-catalyzed decarboxylative oxyalkylation of alkynyl carboxylic acids with ketones and alkylnitriles via direct C(sp3)-H bond functionalization to construct new C-C bonds and C-O double bonds was developed. This transformation is featured by wide functional group compatibility and the use of readily available reagents, thus affording a general approach to ?-diketones and ?-ketonitriles. A possible mechanism is proposed.

Polycondensed Nitrogen Heterocycles. Part 25. Aminopyrrolophenanthridines by Decomposition of 2-(3-Azidophenyl)-1-arylpyrroles

Acid catalyzed decomposition of the azido derivatives 4a-c give rise to amino-hydroxy-phenylpyrroles of type 7 and 8 upon hydrolysis of the intermediate aryl nitrenium ions, together with the hydrogen abstraction compounds of type 3.The aminopyrrolo1,2-f