154503-33-0Relevant articles and documents
Silylene oxonium ylides: di-tert-butylsilylene insertion into C-O bonds
Bourque, Laura E.,Haile, Pamela A.,Loy, Janice M.N.,Woerpel
experimental part, p. 5608 - 5613 (2009/12/01)
Allylic ethers undergo insertions of silylenes into C-O bonds to form allylic silanes. Silylene insertion into C-O acetal bonds was also observed. Formation of silylene ylide intermediates led to [1,2]-Stevens rearrangement products as well as [2,3]-sigma
Cerium(IV), as a selective and efficient catalyst for alcoholyses of allylic and tertiary benzylic alcohols
Iranpoor, Nasser,Mothaghineghad, Enayatholah
, p. 1859 - 1870 (2007/10/02)
An efficient and selective method is described for the catalytic conversion of allylic, and tertiary benzylic alcohols into their corresponding ethers in the presence of Ce(IV) under solvolytic and non- solvolytic conditions.