154550-06-8

Basic information

• Product Name: allyl 2-(allyloxy)-3-methylbenzoate
• Synonyms: allyl 2-(allyloxy)-3-methylbenzoate
• CAS NO: 154550-06-8
• Molecular Weight: 232.279
• Mol File: 154550-06-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: allyl 2-(allyloxy)-3-methylbenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 2-(allyloxy)-3-methylbenzoate(154550-06-8)
• EPA Substance Registry System: allyl 2-(allyloxy)-3-methylbenzoate(154550-06-8)

Safety Data

• Hazardous Substances Data: 154550-06-8(Hazardous Substances Data)

Upstream product

• 83-40-9 3-methylsalicylic acid 
• 106-95-6 allyl bromide 

Downstream Products

• 1412443-87-8 C₃₃H₆₁NO₄Si₂ 
• 1412443-81-2 2-(allyloxy)-N,N-diisopropyl-3-methylbenzamide 
• 1412443-86-7 2-(allyloxy)-6-((5S,6R)-8,8-diethyl-2,2,3,3-tetramethyl-6-((R)-pent-4-en-2-yl)-4,7-dioxa-3,8-disiladecan-5-yl)-N,N-diisopropyl-3-methylbenzamide 
• 1412443-75-4 2-(allyloxy)-6-((1S,2R,3R)-1-hydroxy-3-methyl-2-(triethylsilyloxy)hex-5-enyl)-N,Ndiisopropyl-3-methylbenzamide 
• 153034-30-1 (2-(allyloxy)-3-methylphenyl)methanol 
• 153034-23-2 2-(allyloxy)-3-methylbenzaldehyde 
• 1207288-87-6 3-(2-(allyloxy)-3-methylphenyl)propiolic acid 
• 1207288-86-5 methyl 3-(2-(allyloxy)-3-methylphenyl)propiolate 
• 1207288-85-4 2-(allyloxy)-1-(2,2-dibromovinyl)-3-methylbenzene 
• 154550-02-4 methyl 2-allyloxy-3-methylbenzoate 
• 23287-26-5 3-methylsalicylic acid methyl ester 
• 145526-82-5 2-(allyloxy)-3-methylbenzoic acid 

Relevant articles and documents

Total Synthesis of Ajudazol A by a Modular Oxazole Diversification Strategy

The total synthesis of the potent respiratory chain inhibitor ajudazol A was accomplished by a concise strategy in 17 steps (longest linear sequence). The modular approach was based on a direct oxazole functionalization strategy involving a halogen dance

Full stereochemical determination of ajudazols a and b by bioinformatics gene cluster analysis and total synthesis of ajudazol B by an asymmetric ortholithiation strategy

The stereochemical determination of the potent respiratory chain inhibitors ajudazols A and B and the total synthesis of ajudazol B are reported. Configurational assignment was exclusively based on biosynthetic gene cluster analysis of both ketoreductase

Pyrolysis of O-Allyl Salicylic Amides and Esters, and Related Compounds: Foemation of Isoindolones and Phthalides

Flash vacuum pyrolysis of O-allyl salicylic alkylamides and alkyl esters gives isoindolones and phthalides, respectively, in low (20-40percent) yield.The mechanism involves generation of the phenoxyl radical, regiospecific hydrogen-atom transfer from the alkylamide (or alkyl ester) group and cyclization.A similar sequence was observed with thiophenoxyl radicals.