154828-52-1

Basic information

• Product Name: (3R,4R,5R,6S,7R)-3,4-di-O-benzyl-3,4,5,6,7,8-hexahydroxy-5,6:7,8-di-O-isopropylidene-1-(2-thiazolyl)-1-octanone
• Synonyms: (3R,4R,5R,6S,7R)-3,4-di-O-benzyl-3,4,5,6,7,8-hexahydroxy-5,6:7,8-di-O-isopropylidene-1-(2-thiazolyl)-1-octanone
• CAS NO: 154828-52-1
• Molecular Weight: 567.703
• Mol File: 154828-52-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,4R,5R,6S,7R)-3,4-di-O-benzyl-3,4,5,6,7,8-hexahydroxy-5,6:7,8-di-O-isopropylidene-1-(2-thiazolyl)-1-octanone(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5R,6S,7R)-3,4-di-O-benzyl-3,4,5,6,7,8-hexahydroxy-5,6:7,8-di-O-isopropylidene-1-(2-thiazolyl)-1-octanone(154828-52-1)
• EPA Substance Registry System: (3R,4R,5R,6S,7R)-3,4-di-O-benzyl-3,4,5,6,7,8-hexahydroxy-5,6:7,8-di-O-isopropylidene-1-(2-thiazolyl)-1-octanone(154828-52-1)

Safety Data

• Hazardous Substances Data: 154828-52-1(Hazardous Substances Data)

Upstream product

• 154796-62-0 2-O-benzyl-3,4:5,6-di-O-isopropylidene-D-mannose diethyl dithioacetal 
• 154796-64-2 2-O-benzyl-3,4:5,6-di-O-isopropylidene-aldehydo-D-mannose 
• 136029-16-8 ((2-thiazolylcarbonyl)methyl)triphenylphosphonium bromide 
• 136029-15-7 1-(thiazol-2-yl)-2-(triphenyl-λ ⁵-phosphanylidene)ethan-1-one 
• 6748-69-2 D-mannose diethyl dithioacetal 
• 151204-38-5 3,4:5,6-di-O-isopropylidene-D-mannose diethyl dithioacetal 
• 3458-28-4 D-Mannose 
• 3292-77-1 2-bromo-1-thiazol-2-yl-ethanone 
• 20194-18-7 sodium phenyl-methanolate 
• 154796-74-4 (4R,5R,6S,7R)-4-O-benzyl-4,5,6,7,8-pentahydroxy-5,6:7,8-di-O-isopropylidene-1-(2-thiazolyl)-2(E)-octen-1-one 

Relevant articles and documents

Installation of the pyruvate unit in glycidic aldehydes via a Wittig olefination-Michael addition sequence utilizing a thiazole-armed carbonyl ylid. A new stereoselective route to 3-deoxy-2-ulosonic acids and the total synthesis of DAH, KDN, and 4-epi-KDN

A method for the installation of the (2-thiazolylcarbonyl)methylene group, i.e. a masked pyruvate unit owing to the thiazole to formyl equivalence, in sugar-derived aldehydes has been developed. The strategy involves stereoselective carbon-carbon and carb