154839-99-3Relevant articles and documents
The Intramolecular Enyne Diels-Alder Reaction. Stereoselective Construction of Tricyclic Dioxadienones and Mechanistic Outline
Hoffmann, H. M. R.,Krumwiede, D.,Mucha, B.,Oehlerking, H. H.,Prahst, G. W.
, p. 8999 - 9018 (1993)
4-Methylpent-4-en-2-yn-1-ols and 6-hydroxy-2,3-dihydro-6H-pyran-3-ones are condensed in different ways to a series of tricyclic dioxadienones which contain the basic framework of the cadlinolides A mechanism of the intramolecular enyne-ene cycloisomerization and the origin of the resulting type I and type II dienes is proposed.