1548505-49-2

Basic information

• Product Name: [NiBr(benzylpiperazine dithiocarbamate)(PPh₃)]
• Synonyms: [NiBr(benzylpiperazine dithiocarbamate)(PPh₃)]
• CAS NO: 1548505-49-2
• Molecular Weight: 652.281
• Mol File: 1548505-49-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [NiBr(benzylpiperazine dithiocarbamate)(PPh₃)](CAS DataBase Reference)
• NIST Chemistry Reference: [NiBr(benzylpiperazine dithiocarbamate)(PPh₃)](1548505-49-2)
• EPA Substance Registry System: [NiBr(benzylpiperazine dithiocarbamate)(PPh₃)](1548505-49-2)

Safety Data

• Hazardous Substances Data: 1548505-49-2(Hazardous Substances Data)

Upstream product

• 36673-36-6 dibromobis(triphenylphosphine)nickel(II) 
• 381221-27-8 bis(4-benzylpiperazine-1-carbodithioato-k² S,S')nickel(II) complex 

Relevant articles and documents

Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates:NiX(ndtc)(PPh3)

A series of square-planar nickel(II) benzylpiperazine-dithiocarbamato (bpdtc; 1-4) and thiomorpholine-dithiocarbamato (tmdtc; 5-8) complexes of the composition [NiX(ndtc)(PPh3)] (X symbolizes Cl for 1 and 5, Br for 2 and 6, I for 3 and 7, or NCS for 4 and 8) was prepared and thoroughly characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy, mass spectrometry, molar conductivity and magnetochemical measurements, and by single-crystal X-ray analysis (for complex 1). The solution behaviour study of selected representatives (1, 4, 5 and 8) in various solvents (acetone, acetonitrile, methanol (MeOH), N,N′-dimethylformamide (DMF), chloroform, nitromethane, dimethyl sulfoxide (DMSO), MeOH/water mixture (1:1 v/v)) by a combination of NMR and UV-Vis spectroscopy, mass spectrometry and single-crystal X-ray analysis showed that the complexes decompose back to the synthetic precursors, involving the [Ni(ndtc)2] species, in DMF and DMSO, while they dissolve without a change in their composition in the remaining solvents.