1549795-23-4

Basic information

• Product Name: methyl 2,3-dihydroazulene-3a(1H)-carboxylate
• Synonyms: methyl 2,3-dihydroazulene-3a(1H)-carboxylate
• CAS NO: 1549795-23-4
• Molecular Weight: 190.242
• Mol File: 1549795-23-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2,3-dihydroazulene-3a(1H)-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-dihydroazulene-3a(1H)-carboxylate(1549795-23-4)
• EPA Substance Registry System: methyl 2,3-dihydroazulene-3a(1H)-carboxylate(1549795-23-4)

Safety Data

• Hazardous Substances Data: 1549795-23-4(Hazardous Substances Data)

Upstream product

• 20620-59-1 5-phenyl-n-valeric acid methyl ester 
• 1007586-73-3 methyl 2-diazo-5-phenylpentanoate 

Relevant articles and documents

Asymmetric Synthesis of a 5,7-Fused Ring System Enabled by an Intramolecular Buchner Reaction with Chiral Rhodium Catalyst

A Rh-catalyzed asymmetric intramolecular Buchner ring expansion of α-alkyl-α-diazoesters has been developed. The present protocol generates a 5,7-fused ring system in an enantioselective manner while minimizing β-hydrogen migration, which has been a competing reaction when using α-alkyl-α-diazoesters. The ester functionality at the bridgehead position would be a useful synthetic handle for further derivatization to complex molecules including natural products.