15534-56-2Relevant articles and documents
The Orbital Nature and the Spectral-luminescent and Photochemical Properties of Molecules. V. Radiative and Non-radiative Excited States of Derivatives of Anthraquinone and Their Photochemical Properties
Rudenko, N. A.,Val'kova, G. A.,Shigorin, D. N.,Gorelik, M. V.
, p. 368 - 370 (2007/10/02)
We have studied the mechanism of the photochemical reactions and determined the quantum yield for the photoreduction of 2-R-derivatives of 9,10-anthraquinone (R = H, Br, I, SnEt3) in hexane and ethanol solutions at 293 K.It is shown that the contribution of the orbitals of the substituents to the electronic structure of the radiative and non-radiative excited electronic states of these molecules influences the efficiency of the photo-process.