155366-60-2

Basic information

• Product Name: ethyl-2-(dimethylphenylsilyl)pent-4-enoate
• Synonyms: ethyl-2-(dimethylphenylsilyl)pent-4-enoate
• CAS NO: 155366-60-2
• Molecular Weight: 262.424
• Mol File: 155366-60-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ethyl-2-(dimethylphenylsilyl)pent-4-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl-2-(dimethylphenylsilyl)pent-4-enoate(155366-60-2)
• EPA Substance Registry System: ethyl-2-(dimethylphenylsilyl)pent-4-enoate(155366-60-2)

Safety Data

• Hazardous Substances Data: 155366-60-2(Hazardous Substances Data)

Upstream product

• 13950-56-6 ethyl [2-(dimethylphenyl)silyl]ethanoate 
• 24850-33-7 allyltributylstanane 
• 172913-47-2 (Dimethyl-phenyl-silanyl)-phenylselanyl-acetic acid ethyl ester 
• 106-95-6 allyl bromide 

Downstream Products

• 155366-63-5 2-(dimethylphenylsilyl)pent-4-enol 
• 155366-79-3 4-(dimethylphenylsilyl)hept-6-en-3-one 

Relevant articles and documents

Highly Stereoselective Access to 2,4- and 2,4,5-Substituted Tetrahydrofurans from α-Silylacetic Esters. A Study of Homoallylic Stereocontrol.

Cis-2,4- and cis-cis-2,4,5-substituted tetrahydrofurans have been prepared stereoselectively using electrophile-mediated cyclization of β-hydroxyhomoallylsilanes, readily available from α-silylacetic esters.

Radical allylation of α-silylacetic esters

Allylation of the radical generated from α-silyl-α-phenylselenoacetic esters with various allyltributyltin substrates led to good yields of the corresponding homoallylsilanes. A study on the nature of the radical thus generated was performed using comparative allylation rates with electronically different allyltributyltin compounds. Finally, these homoallylsilanes were converted into the corresponding homoallylic-1,2-diols after reduction of the ester function and oxidation of the C-Si bond.