155433-76-4

Basic information

• Product Name: (E)-3-benzyloxy-1-iodo-7,7-dimethoxy-1-heptene
• CAS NO: 155433-76-4
• Molecular Weight: 390.261
• Mol File: 155433-76-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-3-benzyloxy-1-iodo-7,7-dimethoxy-1-heptene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-benzyloxy-1-iodo-7,7-dimethoxy-1-heptene(155433-76-4)
• EPA Substance Registry System: (E)-3-benzyloxy-1-iodo-7,7-dimethoxy-1-heptene(155433-76-4)

Safety Data

• Hazardous Substances Data: 155433-76-4(Hazardous Substances Data)

Upstream product

• 155433-82-2 7,7-dimethoxyhept-1-yn-3-ol 
• 28995-69-9 6,6-dimethoxyhex-1-ene 
• 50789-30-5 5,5-dimethoxypentanal 
• 764-59-0 hex-5-en-1-al 
• 155433-70-8 3-benzyloxy-7,7-dimethoxy-1-heptyne 

Relevant articles and documents

Stereoselective Synthesis of Alcohols, XLIV. Cyclization of Benzyloxy-Substituted (8-Oxo-2-octenyl)boronates

The cyclization of (8-oxo-2-octenyl)boronates having benzyloxy substituents in the chain linking the two functional groups gives benzyloxy-substituted 2-vinylcyclohexanols.High asymmetric induction is found for the 4- or 6-benzyloxy-(Z)-octenylboronates 12a and 12c, whereas cyclization of the other isomers studied proceeded in a stereorandom fashion.Possible reasons for this unexpected behavior are discussed. - Key Words: Cyclization, stereoselective / Allylboration, intramolecular / Transition state conformations, polar effects on / Boronates