155720-51-7Relevant articles and documents
Naphthodifluorene derivative Light-emitting material, light-emitting element, and consumer-type product
-
Paragraph 0049, (2021/09/26)
The invention relates to a naphthodifluorene derivative, a luminescent material, a light-emitting element and a consumer-type product, wherein the I derivative is suitable for an electronic element, particularly suitable for an organic electroluminescent device, and relates to a material for an organic electroluminescent element, an organic electroluminescent device and an electronic device containing the compound. When used as a matrix material of a fluorescent or phosphorescent luminous body, the derivative has very high efficiency and long service life, and the derivative has high efficiency and a steep current - voltage curve under the condition of using and low operating voltage.
Silver-Catalyzed Selective Multicomponent Coupling Reactions of Arynes with Nitriles and Isonitriles
Ghorai, Sourav,Lin, Yongjia,Xia, Yuanzhi,Wink, Donald J.,Lee, Daesung
supporting information, p. 642 - 647 (2020/01/31)
Pathway selective aryne-based novel multicomponent coupling reactions with isonitriles and nitriles are described. Crucial to these reactions is the formation of a silver-aryne complex, which shows differential reactivity toward isonitriles and nitriles to form two different forms of ortho-nitrilium organosilver arene species. Interception of the nitrilium of an aryne-isonitrile adduct with another isonitrile leads to the formation of benzocyclobutene-1,2-diimines, whereas the nitrilium of an aryne-nitrile adduct renders selective formation of 3H-indol-3-imines or 3-iminoindolin-2-ol depending on the structure of the nitrile employed.
Synthesis of Fluorescent Azafluorenones and Derivatives via a Ruthenium-Catalyzed [2 + 2 + 2] Cycloaddition
Ye, Fei,Tran, Christine,Jullien, Ludovic,Le Saux, Thomas,Haddad, Mansour,Michelet, Véronique,Ratovelomanana-Vidal, Virginie
supporting information, p. 4950 - 4953 (2018/08/24)
An original and mild synthetic route for the preparation of novel azafluorenones and derivatives via a ruthenium-mediated [2 + 2 + 2] cycloaddition of α,ω-diynes and cyanamides has been developed. This atom-economical catalytic process demonstrated remarkable regioselectivities to access fluorescent azafluorenone derivatives. The photophysical properties of azafluorenone derivatives have been evaluated, and photoluminescence phenomena at solid and liquid states have been highlighted.