155780-34-0Relevant articles and documents
Reaction of Silyl Enol Ethers with Arenediazonium Salts. Part 2. α-Amination of Esters
Sakakura, Toshiyasu,Hara, Masayasu,Tanaka, Masato
, p. 289 - 294 (1994)
Diazonium salts efficiently serve as electrophilic aminating reagents of esters.The reaction of arenediazonium tetrafluoroborates with ketene silyl ketals yielded α-azo or α-hydrazono esters in good to excellent yields under very mild conditions.Hydrogenation of those esters gave α-amino esters quantitatively.