1560-06-1Relevant articles and documents
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Arnold,Liggett
, p. 337 (1945)
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Wilson,Roberts,Young
, p. 2019 (1949)
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CROSS COUPLING OF PHENYLMANGANESE IODIDE WITH ALLYL AND PROPARGYL ACETATES
Kresteleva, I. V.,Spivak, A. Yu.,Tolstikov, G. A.
, p. 424 (1987)
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Asymmetric Palladium-Catalyzed Oxycarbonylation of Terminal Alkenes: Efficient Access to β-Hydroxy Alkylcarboxylic Acids
Tian, Bing,Li, Xiang,Chen, Pinhong,Liu, Guosheng
supporting information, p. 14881 - 14886 (2021/06/09)
A novel PdII-catalyzed enantioselective oxycarbonylation of alkenes has been established. The ligand with an ethyl group at the C-6 position of Pyox plays a significant role in the intermolecular oxypalladation process, leading to high reactivity and excellent enantioselective control. Compared to the conventional methods, the reaction itself features alkenes as easily prepared starting materials, mild and operationally simple reaction conditions, and insensitivities to air and water. Moreover, this method allows for broad alkene substrate scope, excellent regio- and enantioselectivities, scalabilities and a wide array of applications, and provides a useful route for the convenient and straightforward synthesis of chiral β-hydroxy alkylcarboxylic acids/esters.
Reduction of α,β-unsaturated carbonyl compounds and 1,3-diketones in aqueous media, using a raney ni-al alloy
Simion, Cristian,Mitoma, Yoshiharu,Katayama, Yumi,Simion, Alina Marieta
, p. 51 - 55 (2021/02/03)
The treatment of α,β-unsaturated carbonyl compounds and 1,3-diketones with Raney Ni-Al alloy in aqueous media yielded as major reaction products the corresponding saturated alcohols and/or the corresponding hydrocarbons, in a complete transformation of the starting material.
Reduction of α,β-Unsaturated carbonyl compounds and 1,3-Diketones in aqueous media, using a raney ni-al alloy
Katayama, Yumi,Mitoma, Yoshiharu,Simion, Alina Marieta,Simion, Cristian
, p. 51 - 55 (2020/07/23)
The treatment of α,β-unsaturated carbonyl compounds and 1,3-diketones with Raney Ni-Al alloy in aqueous media yielded as major reaction products the corresponding saturated alcohols and/or the corresponding hydrocarbons, in a complete transformation of the starting material.