15600-32-5

Basic information

• Product Name: Carbonochloridic acid, 1-phenylethyl ester
• Synonyms: (+/-)-Kohlensaeure-(1-phenyl-aethylester)-chlorid;Chlorokohlensaeure-(1-phenyl-aethylester);chlorocarbonic acid-(1-phenyl-ethyl ester);(+/-)-Chlorameisensaeure-(1-phenyl-aethylester);(+/-)-(1-Phenyl-aethyl)-chlorformiat;1-phenylethyl chloroformate
• CAS NO: 15600-32-5
• Molecular Formula: C9H9ClO2
• Molecular Weight: 184.622
• Mol File: 15600-32-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Carbonochloridic acid, 1-phenylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonochloridic acid, 1-phenylethyl ester(15600-32-5)
• EPA Substance Registry System: Carbonochloridic acid, 1-phenylethyl ester(15600-32-5)

Safety Data

• Hazardous Substances Data: 15600-32-5(Hazardous Substances Data)

Upstream product

• 75-44-5 phosgene 
• 98-85-1 1-Phenylethanol 
• 108-88-3 toluene 
• 503-38-8 trichloromethyl chloroformate 
• 32315-10-9 bis(trichloromethyl) carbonate 

Downstream Products

• 2605-18-7 1-methoxy-4-(1-phenylethyl)benzene 
• 1017848-58-6 4-benyl-2-(4-methoxyphenyl)oxazol-5-yl 1-phenylethyl carbonate 
• 1017848-55-3 2-(4-methoxyphenyl)-4-methyloxazol-5-yl 1-phenylethyl carbonate 
• 265659-68-5 α-methylbenzyl azidoformate 
• 141036-94-4 benzyl (α-methylbenzyl) carbonate 
• 13371-24-9 triphenyl-(1-phenyl-ethyl)-phosphonium; chloride 
• 672-65-1 (1-chloroethyl)benzene 

Relevant articles and documents

Deoxygenative cross-electrophile coupling of benzyl chloroformates with aryl iodides

This work describes Ni-catalyzed cross-electrophile coupling of benzyl chloroformate derivatives with aryl iodides that generates a wide range of diaryl methane products. The mild reaction conditions merit the C-O bond radical fragmentation of benzyl chloroformates via halide abstraction or a single electron reduction by a Ni catalyst. This work offers a new substrate type for cross-electrophile couplings.

A facile synthesis of azidoformate via chloroformate

This work synthesized chloroformates by slowly adding alcohols into a suspension of trichloromethyl chloroformate, instead of phosgene, along with activated charcoal in tetrahydrofuran. This chloroformylation yielded chloroformates in near quantitative yield. The subsequent reaction between chloroformates and sodium azide in dry acetone produced azidoformates in a high yield.