156039-18-8

Basic information

• Product Name: S-ethyl (2S,3R)-3-hydroxy-2-methyl-5-phenylpentanethioate
• Synonyms: S-ethyl (2S,3R)-3-hydroxy-2-methyl-5-phenylpentanethioate
• CAS NO: 156039-18-8
• Molecular Weight: 252.378
• Mol File: 156039-18-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: S-ethyl (2S,3R)-3-hydroxy-2-methyl-5-phenylpentanethioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-ethyl (2S,3R)-3-hydroxy-2-methyl-5-phenylpentanethioate(156039-18-8)
• EPA Substance Registry System: S-ethyl (2S,3R)-3-hydroxy-2-methyl-5-phenylpentanethioate(156039-18-8)

Safety Data

• Hazardous Substances Data: 156039-18-8(Hazardous Substances Data)

Upstream product

• 75-08-1 ethanethiol 
• 104-53-0 3-phenyl-propionaldehyde 
• 63584-42-9 (Z)-1-ethylthio-1-(trimethylsiloxy)propene 
• 123-72-8 butyraldehyde 

Downstream Products

• 1376112-37-6 (2S,3R)-3-hydroxy-2-methyl-5-phenylpentanoic acid 

Relevant articles and documents

Facile removal of 4-phenyl-oxazolidinethione auxiliary with EtSH mediated by DBU

N-Acyl-β-hydroxy-4-phenyl-oxazolidinethiones could be rapidly converted into thioesters in high yields by treatment with EtSH/DBU at 0°C.

The catalytic asymmetric aldol reaction of aldehydes with unsubstituted and monosubstituted silyl ketene acetals: Formation of anti-β-hydroxy-α-methyl esters

The title rection with unsubstituted and monosubstituted silyl ketene acetals proceeds with high enantioselectivity, and in the latter case good diastereoselectivity favoring the anti-β-hydroxy-α-methyl esters in all reported cases.